Zinc Dimethyldithiocarbamate

Basic Info

Common NameZinc Dimethyldithiocarbamate(F04280)
2D Structure
Description

Zinc dimethyldithiocarbamate is a chemical compound of zinc. Zinc is a metallic element with the atomic number 30. It is found in nature most often as the mineral sphalerite. Though excess zinc in harmful, in smaller amounts it is an essential element for life, as it is a cofactor for over 300 enzymes and is found in just as many transcription factors. (L48, L49)

FRCD IDF04280
CAS Number137-30-4
PubChem CID8722
FormulaC6H12N2S4Zn
IUPAC Name

zinc;N,N-dimethylcarbamodithioate

InChI Key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

InChI

InChI=1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

Canonical SMILES

CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Zn+2]

Isomeric SMILES

CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Zn+2]

Synonyms
        
            Zinc dimethyldithiocarbamate
        
            ZIRAM
        
            137-30-4
        
            Carbazinc
        
            Fuclasin
        
            Methazate
        
            Zarlate
        
            Aazira
        
            Cymate
        
            Tsimat
Classifies
                

                  
                    Pollutant
                  
                    Pesticide
Update DateNov 13, 2018 17:07

Chemical Taxonomy

KingdomOrganic compounds
SuperclassOrganic salts
ClassOrganic metal salts
SubclassOrganic transition metal salts
Intermediate Tree NodesNot available
Direct ParentOrganic transition metal salts
Alternative Parents
Molecular FrameworkNot available
SubstituentsOrganic transition metal salt - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organosulfur compound - Organonitrogen compound - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as organic transition metal salts. These are organic salt compounds containing a transition metal atom in its ionic form.

Properties

Property NameProperty Value
Molecular Weight305.796
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count4
Rotatable Bond Count0
Complexity54.3
Monoisotopic Mass303.917
Exact Mass303.917
Formal Charge0
Heavy Atom Count13
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
Isotope Atom Count0
Covalently-Bonded Unit Count3

MRLs

FoodProduct CodeCountryMRLsApplication DateNotes
BeetsCanada7mg/kg
TomatoBelgium3.00mg/kg
AuberginesIsrael3mg/kg
BlackberriesCanada7mg/kg
CabbageIsrael5mg/kg
BeansCanada7mg/kg
Hort BrassicaAustria2.00mg/kg
Strawberries (Other Than Wild)Austria2.00mg/kg
GooseberriesAustria2.00mg/kg
GarlicAustria0.50mg/kg
Hort BrassicaBelgium2.00mg/kg
Macadamia NutsAustralia0.2mg/kg
Strawberries (Other Than Wild)Belgium2.00mg/kg
Citrus FruitsAustria2.00mg/kg
GooseberriesBelgium5.00mg/kg
GarlicBelgium0.50mg/kg
CarrotsAustria2.00mg/kg
BeansBelgium1.00mg/kg
CucumbersAustria0.50mg/kg
PlumsAustria1.00mg/kg

References

TitleJournalDatePubmed ID
Metabolic Effects of a Chronic Dietary Exposure to a Low-Dose Pesticide Cocktail in Mice: Sexual Dimorphism and Role of the Constitutive Androstane Receptor.Environ Health Perspect2018 Jun 2529950287
Combined exposure to low doses of pesticides causes decreased birth weights inrats.Reprod Toxicol2017 Sep28526456
Preparation and characterization of magnetic carboxylated nanodiamonds forvortex-assisted magnetic solid-phase extraction of ziram in food and watersamples.Talanta2016 Sep 127343589
Sensitive bi-enzymatic biosensor based on polyphenoloxidases-goldnanoparticles-chitosan hybrid film-graphene doped carbon paste electrode forcarbamates detection.Bioelectrochemistry2014 Aug24642204
Laccase-Prussian blue film-graphene doped carbon paste modified electrode forcarbamate pesticides quantification.Biosens Bioelectron2013 Sep 1523587791
Selective determination of thiram residues in fruit and vegetables by hydrophilicinteraction LC-MS.Food Addit Contam Part A Chem Anal Control Expo Risk Assess201324070320
Method validation and analysis of nine dithiocarbamates in fruits and vegetables by LC-MS/MS.Food Addit Contam Part A Chem Anal Control Expo Risk Assess201323799268
Direct analysis of dithiocarbamate fungicides in fruit by ambient massspectrometry.Food Addit Contam Part A Chem Anal Control Expo Risk Assess2011Oct21749227
Induction of tibial dyschondroplasia by carbamate and thiocarbamate pesticides.Avian Dis2007 Jun17626489
Column preconcentration and spectrophotometric determination of ziram and zinebin commercial samples and foodstuffs using (1,2'-pyridylazo)-2-naphthol(PAN)-naphthalene as adsorbate.J Agric Food Chem2004 Dec 2915612751
Microwave-assisted extraction (MAE)-acid hydrolysis of dithiocarbamates for traceanalysis in tobacco and peaches.J Agric Food Chem2002 Apr 1011929274
Determination of dithiocarbamate fungicide residues in food by aspectrophotometric method using a vertical disulfide reaction system.J Agric Food Chem2001 Oct11599982
Spectrophotometric determination of ferbam [iron(III) dimethyl dithiocarbamate]in commercial sample and wheat grains after extraction of its bathophenanthrolinetetraphenylborate complex into molten naphthalene.J Agric Food Chem2000 Sep10995311
Simple and sensitive spectrophotometric determination of ziram, zineb and ferbam in commercial samples and foodstuffs using phenylfluorone.J Environ Monit2000 Aug11249794
Genotoxicity of dithiocarbamates and their metabolites.Mutat Res1994 Nov7523933
Effect of pretreatment with hepatic mixed-function oxidase inducers on thegenotoxicity of four rat carcinogens in the hepatocyte/DNA repair assay.Mutagenesis1990 Jul2169015