Aluminium Phosphide
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Basic Info
| Common Name | Aluminium Phosphide(F04284) |
| 2D Structure | |
| Description | Aluminium phosphide is a phosphide of aluminum. It is a wide band gap semiconductor and is used as a rodenticide, insecticide and fumigant for stored cereal grains. Aluminum is the most abundant metal in the earth's crust and is always found combined with other elements such as oxygen, silicon, and fluorine. Metal phosphides are hydrolysed to phosphine upon contact with water or stomach acid. Phosphine is a colorless, flammable, explosive, and toxic gas. (L980, L739, L740, L770) |
| FRCD ID | F04284 |
| CAS Number | 20859-73-8 |
| PubChem CID | 30332 |
| Formula | AlP |
| IUPAC Name | alumanylidynephosphane |
| InChI Key | PPNXXZIBFHTHDM-UHFFFAOYSA-N |
| InChI | InChI=1S/Al.P |
| Canonical SMILES | [Al]#P |
| Isomeric SMILES | [Al]#P |
| Synonyms |
Celphine
Delicia gastoxin
ALUMINUM PHOSPHIDE
Aluminium phosphide
Phostoxin
20859-73-8
Celphide
Celphos
Fumitoxin
Delicia
|
| Classifies |
Illegal Additives
Pesticide
|
| Update Date | Nov 13, 2018 17:07 |
Chemical Taxonomy
| Kingdom | Inorganic compounds |
| Superclass | Mixed metal/non-metal compounds |
| Class | Miscellaneous mixed metal/non-metals |
| Subclass | Not available |
| Intermediate Tree Nodes | Not available |
| Direct Parent | Miscellaneous mixed metal/non-metals |
| Alternative Parents | |
| Molecular Framework | Not available |
| Substituents | Inorganic phosphide - Miscellaneous mixed metal/non-metal |
| Description | This compound belongs to the class of inorganic compounds known as miscellaneous mixed metal/non-metals. These are inorganic compounds containing non-metal as well as metal atoms but not belonging to afore mentioned classes. |
Properties
| Property Name | Property Value |
|---|---|
| Molecular Weight | 57.955 |
| Hydrogen Bond Donor Count | 0 |
| Hydrogen Bond Acceptor Count | 0 |
| Rotatable Bond Count | 0 |
| Complexity | 10 |
| Monoisotopic Mass | 57.955 |
| Exact Mass | 57.955 |
| Formal Charge | 0 |
| Heavy Atom Count | 2 |
| Defined Atom Stereocenter Count | 0 |
| Undefined Atom Stereocenter Count | 0 |
| Defined Bond Stereocenter Count | 0 |
| Undefined Bond Stereocenter Count | 0 |
| Isotope Atom Count | 0 |
| Covalently-Bonded Unit Count | 1 |
MRLs
| Food | Product Code | Country | MRLs | Application Date | Notes |
|---|---|---|---|---|---|
| Honey | Australia | 0.01mg/kg | |||
| Fruits,Dried | Australia | 0.01mg/kg | |||
| Simazine | Australia | 0.01mg/kg | |||
| Melon | Australia | 0.01mg/kg | |||
| Peanuts | Australia | 0.01mg/kg | |||
| Cacao Bean | Australia | 0.01mg/kg | |||
| Spices | Australia | 0.01mg/kg | |||
| Soya Bean | Korea | 0.1ppm | |||
| Barley | Korea | 0.1ppm | |||
| Rice | Korea | 00.1ppm | |||
| Rye | Korea | 0.1ppm | |||
| Walnuts | Korea | 0.01ppm | |||
| Peanuts | Korea | 0.01ppm | |||
| Wheat | Korea | 0.1ppm | |||
| Almonds | Korea | 0.01ppm | |||
| Oats | Korea | 0.1ppm | |||
| Maize | Korea | 0.1ppm |
References
| Title | Journal | Date | Pubmed ID |
|---|---|---|---|
| Inhalation of phosphine gas following a fire associated with fumigation ofprocessed pistachio nuts. | J Agromedicine | 2013 | 23540306 |
| Death by caffeine: presumptive malicious poisoning of a dog by incorporation inground meat. | J Med Toxicol | 2012 Dec | 23104127 |
| Phosphine intoxication following oral exposure of horses to aluminumphosphide-treated feed. | J Am Vet Med Assoc | 2010 Feb 15 | 20151871 |
| Influence of environmental, structural, and behavioral factors on the presence ofphosphine in worker areas during fumigations in grain elevators. | J Agric Saf Health | 2001 Feb | 11398899 |
| Determination of phosphine residues in whole grains and soybeans by ionchromatography via conversion to phosphate. | J AOAC Int | 1998 Nov-Dec | 9850582 |
| Cardiovascular manifestations of aluminium phosphide intoxication. | J Assoc Physicians India | 1989 Sep | 2632560 |