Propineb
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Basic Info
| Common Name | Propineb(F05780) |
| 2D Structure | |
| FRCD ID | F05780 |
| CAS Number | 12071-83-9 |
| PubChem CID | 3032571 |
| Formula | C5H8N2S4Zn |
| IUPAC Name | zinc;N-[1-(sulfidocarbothioylamino)propan-2-yl]carbamodithioate |
| InChI Key | KKMLIVYBGSAJPM-UHFFFAOYSA-L |
| InChI | InChI=1S/C5H10N2S4.Zn/c1-3(7-5(10)11)2-6-4(8)9;/h3H,2H2,1H3,(H2,6,8,9)(H2,7,10,11);/q;+2/p-2 |
| Canonical SMILES | CC(CNC(=S)[S-])NC(=S)[S-].[Zn+2] |
| Isomeric SMILES | CC(CNC(=S)[S-])NC(=S)[S-].[Zn+2] |
| Synonyms |
Propineb
Propinebe
Airone
Taifen
Antracol
Propylenebis(dithiocarbamato)zinc
Methylzineb
Mezineb
12071-83-9
Bayer 46131
|
| Classifies |
Pesticide
|
| Update Date | Nov 13, 2018 17:07 |
Chemical Taxonomy
| Kingdom | Organic compounds |
| Superclass | Organic salts |
| Class | Organic metal salts |
| Subclass | Organic transition metal salts |
| Intermediate Tree Nodes | Not available |
| Direct Parent | Organic transition metal salts |
| Alternative Parents | |
| Molecular Framework | Aliphatic acyclic compounds |
| Substituents | Organic transition metal salt - Organic 1,3-dipolar compound - Propargyl-type 1,3-dipolar organic compound - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organosulfur compound - Organonitrogen compound - Aliphatic acyclic compound |
| Description | This compound belongs to the class of organic compounds known as organic transition metal salts. These are organic salt compounds containing a transition metal atom in its ionic form. |
Properties
| Property Name | Property Value |
|---|---|
| Molecular Weight | 289.753 |
| Hydrogen Bond Donor Count | 2 |
| Hydrogen Bond Acceptor Count | 4 |
| Rotatable Bond Count | 0 |
| Complexity | 164 |
| Monoisotopic Mass | 287.886 |
| Exact Mass | 287.886 |
| Formal Charge | 0 |
| Heavy Atom Count | 12 |
| Defined Atom Stereocenter Count | 0 |
| Undefined Atom Stereocenter Count | 1 |
| Defined Bond Stereocenter Count | 0 |
| Undefined Bond Stereocenter Count | 0 |
| Isotope Atom Count | 0 |
| Covalently-Bonded Unit Count | 2 |
MRLs
| Food | Product Code | Country | MRLs | Application Date | Notes |
|---|---|---|---|---|---|
| Cucumbers | Korea | 0.5ppm | |||
| Watermelons | Korea | 0.3ppm | |||
| Onions | Korea | 0.3ppm | |||
| Sesame Seeds | Korea | 2ppm | |||
| Citrus fruits | 0110000 | European Union | 0.05* | 01/09/2008 | |
| Grapefruits (Natsudaidais, Shaddocks/pomelos, Sweeties/oroblancos, Tangelolos, Tangelos (except minneolas)/Ugli®, Other hybrids of Citrus paradisi, not elsewhere mentioned,) | 0110010 | European Union | 0.05* | 01/09/2008 | |
| Oranges (Bergamots, Bitter oranges/sour oranges, Blood oranges, Cara caras, Chinottos, Trifoliate oranges, Other hybrids of Citrus sinensis, not elsewhere mentioned,) | 0110020 | European Union | 0.05* | 01/09/2008 | |
| Lemons (Buddha's hands/Buddha's fingers, Citrons,) | 0110030 | European Union | 0.05* | 01/09/2008 | |
| Others (2) | 0870990 | European Union | 0.1* | 01/09/2008 | |
| Others (2) | 0110990 | European Union | 0.05* | 01/09/2008 | |
| Tree nuts | 0120000 | European Union | 0.05* | 01/09/2008 | |
| Almonds (Apricot kernels, Bitter almonds, Canarium nuts/galip nuts, Pili nuts, Okari nuts,) | 0120010 | European Union | 0.05* | 01/09/2008 | |
| Brazil nuts | 0120020 | European Union | 0.05* | 01/09/2008 | |
| Cashew nuts | 0120030 | European Union | 0.05* | 01/09/2008 | |
| Chestnuts | 0120040 | European Union | 0.05* | 01/09/2008 | |
| Coconuts (Areca nuts/betel nuts,) | 0120050 | European Union | 0.05* | 01/09/2008 | |
| Hazelnuts/cobnuts (Acorns, Filberts,) | 0120060 | European Union | 0.05* | 01/09/2008 | |
| Macadamias | 0120070 | European Union | 0.05* | 01/09/2008 | |
| Pecans (Hickory nuts,) | 0120080 | European Union | 0.05* | 01/09/2008 | |
| Pistachios | 0120100 | European Union | 0.05* | 01/09/2008 |
References
| Title | Journal | Date | Pubmed ID |
|---|---|---|---|
| Determination of propineb and its metabolites propylenethiourea andpropylenediamine in banana and soil using gas chromatography with flamephotometric detection and LC-MS/MS analysis. | J Environ Sci Health B | 2018 Mar 4 | 29227190 |
| Multi-residue analysis of pesticides, plant hormones, veterinary drugs and mycotoxins using HILIC chromatography - MS/MS in various food matrices. | Anal Chim Acta | 2016 Oct 26 | 27720116 |
| Method validation and analysis of nine dithiocarbamates in fruits and vegetables by LC-MS/MS. | Food Addit Contam Part A Chem Anal Control Expo Risk Assess | 2013 | 23799268 |
| [Determination of 4 dithiocarbamate residues in 22 matrices by gaschromatography]. | Se Pu | 2010 Dec | 21438370 |
| Determination of dithiocarbamates and milneb residues in foods by gaschromatography-mass spectrometry. | Shokuhin Eiseigaku Zasshi | 2010 | 21071904 |
| Dietary exposure of Brazilian consumers to dithiocarbamate pesticides--aprobabilistic approach. | Food Chem Toxicol | 2006 Sep | 16777311 |