Ferbam

Basic Info

Common NameFerbam(F06176)
2D Structure
FRCD IDF06176
CAS Number14484-64-1
PubChem CID26710
FormulaC9H18FeN3S6
IUPAC Name

N,N-dimethylcarbamodithioate;iron(3+)

InChI Key

WHDGWKAJBYRJJL-UHFFFAOYSA-K

InChI

InChI=1S/3C3H7NS2.Fe/c3*1-4(2)3(5)6;/h3*1-2H3,(H,5,6);/q;;;+3/p-3

Canonical SMILES

CN(C)C(=S)[S-].CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Fe+3]

Isomeric SMILES

CN(C)C(=S)[S-].CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Fe+3]

Synonyms
        
            Ferbam
        
            Fermacide
        
            Iron(III) dimethyldithiocarbamate
        
            Ferric dimethyldithiocarbamate
        
            14484-64-1
        
            Trimanzone
        
            Cormate
        
            Fermate
        
            Ferradow
        
            Hexaferb
Classifies
                

                  
                    Pesticide
Update DateNov 13, 2018 17:07

Chemical Taxonomy

KingdomOrganic compounds
SuperclassOrganic salts
ClassOrganic metal salts
SubclassOrganic transition metal salts
Intermediate Tree NodesNot available
Direct ParentOrganic transition metal salts
Alternative Parents
Molecular FrameworkNot available
SubstituentsOrganic transition metal salt - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organosulfur compound - Organonitrogen compound - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as organic transition metal salts. These are organic salt compounds containing a transition metal atom in its ionic form.

Properties

Property NameProperty Value
Molecular Weight416.469
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count6
Rotatable Bond Count0
Complexity54.3
Monoisotopic Mass415.917
Exact Mass415.917
Formal Charge0
Heavy Atom Count19
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
Isotope Atom Count0
Covalently-Bonded Unit Count4

MRLs

FoodProduct CodeCountryMRLsApplication DateNotes
ApplesCanada7mg/kg
ApricotsCanada7mg/kg
AsparagusCanada7mg/kg
BeansCanada7mg/kg
BeetsCanada7mg/kg
BlackberriesCanada7mg/kg
Blackeyed PeasCanada7mg/kg
BlueberriesCanada7mg/kg
BroccoliCanada7mg/kg
Brussels SproutsCanada7mg/kg
CabbagesCanada7mg/kg
CarrotsCanada7mg/kg
CauliflowerCanada7mg/kg
CeleryCanada7mg/kg
CherriesCanada7mg/kg
CollardsCanada7mg/kg
CornCanada7mg/kg
CranberriesCanada7mg/kg
CucumbersCanada7mg/kg
CurrantsCanada7mg/kg

References

TitleJournalDatePubmed ID
Investigation of Pesticide Penetration and Persistence on Harvested and LiveBasil Leaves Using Surface-Enhanced Raman Scattering Mapping.J Agric Food Chem2017 May 328393527
Evaluation of the Penetration of Multiple Classes of Pesticides in Fresh Produce Using Surface-Enhanced Raman Scattering Mapping.J Food Sci2016 Oct 627711977
Real-Time and in Situ Monitoring of Pesticide Penetration in Edible Leaves bySurface-Enhanced Raman Scattering Mapping.Anal Chem2016 May 1727099952
Alteration of the Nonsystemic Behavior of the Pesticide Ferbam on Tea Leaves byEngineered Gold Nanoparticles.Environ Sci Technol2016 Jun 2127254832
Surface-enhanced Raman scattering detection of silver nanoparticles inenvironmental and biological samples.Sci Total Environ2016 Jun 126956173
A Filter-based Surface Enhanced Raman Spectroscopic Assay for Rapid Detection of Chemical Contaminants.J Vis Exp2016 Feb 1926966831
Analysis of silver nanoparticles in antimicrobial products using surface-enhancedRaman spectroscopy (SERS).Environ Sci Technol2015 Apr 725775209
Semi-quantification of surface-enhanced Raman scattering using a handheld Ramanspectrometer: a feasibility study.Analyst2013 Dec 724066350
Method validation and analysis of nine dithiocarbamates in fruits and vegetables by LC-MS/MS.Food Addit Contam Part A Chem Anal Control Expo Risk Assess201323799268
Capillary electrophoretic-ultraviolet method for the separation and estimation ofzineb, maneb, and ferbam in food samples.J AOAC Int2007 May-Jun17580637
Induction of tibial dyschondroplasia by carbamate and thiocarbamate pesticides.Avian Dis2007 Jun17626489
Spectrophotometric determination of ferbam [iron(III) dimethyl dithiocarbamate]in commercial sample and wheat grains after extraction of its bathophenanthrolinetetraphenylborate complex into molten naphthalene.J Agric Food Chem2000 Sep10995311
Simple and sensitive spectrophotometric determination of ziram, zineb and ferbam in commercial samples and foodstuffs using phenylfluorone.J Environ Monit2000 Aug11249794
High-performance liquid chromatographic determination of dimethyldithiocarbamate residues in some agricultural products.J Chromatogr1986 Feb 283009509
Oral toxicity of ferric dimethyl-dithiocarbamate (ferbam) and tetramethylthiuram disulfide (thiram) in rodents.J Toxicol Environ Health1978 Jan633415