Enzyme

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     1. Oxidoreductases
        1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
            1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
ID:1.14.14.110
Description:2-hydroxy-1,4-benzoxazin-3-one monooxygenase.
Alternative Name: CYP71C3.

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 1.14.14.110
BRENDA Enzyme Link: BRENDA 1.14.14.110
KEGG Enzyme Link: KEGG1.14.14.110
BioCyc Enzyme Link: BioCyc 1.14.14.110
ExPASy Enzyme Link: ExPASy1.14.14.110
EC2PDB Enzyme Link: EC2PDB 1.14.14.110
ExplorEnz Enzyme Link: ExplorEnz 1.14.14.110
PRIAM enzyme-specific profiles Link: PRIAM 1.14.14.110
IntEnz Enzyme Link: IntEnz 1.14.14.110
MEDLINE Enzyme Link: MEDLINE 1.14.14.110
MSA:

1.14.14.110;

Phylogenetic Tree:

1.14.14.110;

Uniprot:
M-CSA:
RHEA:31939 2-hydroxy-2H-1,4-benzoxazin-3(4H)-one + O2 + reduced [NADPH--hemoprotein reductase] = DIBOA + H(+) + H2O + oxidized [NADPH--hemoprotein reductase]
RULE(radius=1) [*:1]-[N;H0;+0:2]1-[CH;+0:3]=[C;H0;+0:4](-[*:5])-[CH2;+0:6]-[CH;+0:7]=[CH;+0:8]-1.[*:9]-[NH;+0:10]-[*:11].[H+;H0:12].[O;H0;+0:13]=[O;H0;+0:14]>>[*:9]-[N;H0;+0:10](-[*:11])-[OH;+0:13].[*:1]-[n+;H0:2]1:[cH;+0:3]:[c;H0;+0:4](-[*:5]):[cH;+0:6]:[cH;+0:7]:[cH;+0:8]:1.[OH2;+0:14]
Reaction
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References

TitleAuthorsDatePubMed ID
Maize microsomal benzoxazinone N-monooxygenase.Bailey BA, Larson RL1991 Mar16668055
Cytochrome P450 monooxygenases of DIBOA biosynthesis: specificity and conservation among grasses.Glawischnig E, Grün S, Frey M, Gierl A1999 Mar10385992