EC number:1.14.14.135
Enzyme
Download| EC Tree |
| 1. Oxidoreductases |
| 1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen |
| 1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor |
| ID: | 1.14.14.135 | ||
|---|---|---|---|
| Description: | Glyceollin synthase. | ||
| Alternative Name: |
Dimethylallyl-3,6a,9-trihydroxypterocarpan cyclase. | ||
| Prosite: | PDOC00081; | ||
| PDB: |
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3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 1.14.14.135 |
| BRENDA Enzyme Link: | BRENDA 1.14.14.135 |
| KEGG Enzyme Link: | KEGG1.14.14.135 |
| BioCyc Enzyme Link: | BioCyc 1.14.14.135 |
| ExPASy Enzyme Link: | ExPASy1.14.14.135 |
| EC2PDB Enzyme Link: | EC2PDB 1.14.14.135 |
| ExplorEnz Enzyme Link: | ExplorEnz 1.14.14.135 |
| PRIAM enzyme-specific profiles Link: | PRIAM 1.14.14.135 |
| IntEnz Enzyme Link: | IntEnz 1.14.14.135 |
| MEDLINE Enzyme Link: | MEDLINE 1.14.14.135 |
EC number:1.14.14.135
| MSA: | |
|---|---|
| Phylogenetic Tree: | |
| Uniprot: | |
| M-CSA: |
| RHEA:22844 | (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan + O2 + reduced [NADPH--hemoprotein reductase] = glyceollin I + H(+) + 2 H2O + oxidized [NADPH--hemoprotein reductase] |
| RULE(radius=1) | [*:1]-[C;H0;+0:2](-[*:3])=[CH;+0:4]-[CH2;+0:5]-[*:6]:[*:7]-[OH;+0:8].[*:9]-[N;H0;+0:10]1-[CH;+0:11]=[C;H0;+0:12](-[*:13])-[CH2;+0:14]-[CH;+0:15]=[CH;+0:16]-1.[H+;H0:17].[O;H0;+0:18]=[O;H0;+0:19]>>[*:1]-[C;H0;+0:2]1(-[*:3])-[CH;+0:4]=[CH;+0:5]-[*:6]:[*:7]-[O;H0;+0:8]-1.[*:9]-[n+;H0:10]1:[cH;+0:11]:[c;H0;+0:12](-[*:13]):[cH;+0:14]:[cH;+0:15]:[cH;+0:16]:1.[OH2;+0:18].[OH2;+0:19] |
| Reaction |  |
| Core-to-Core | |
| Core-to-Core |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Induction of phytoalexin synthesis in soybean: enzymatic cyclization of prenylated pterocarpans to glyceollin isomers. | Welle R, Grisebach H | 1988 May 15 | 3369863 |
| RHEA:26047 | (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + O2 + reduced [NADPH--hemoprotein reductase] = glyceollin II + H(+) + 2 H2O + oxidized [NADPH--hemoprotein reductase] |
| RULE(radius=1) | [*:1]-[C;H0;+0:2](-[*:3])=[CH;+0:4]-[CH2;+0:5]-[*:6]:[*:7]-[OH;+0:8].[*:9]-[N;H0;+0:10]1-[CH;+0:11]=[C;H0;+0:12](-[*:13])-[CH2;+0:14]-[CH;+0:15]=[CH;+0:16]-1.[H+;H0:17].[O;H0;+0:18]=[O;H0;+0:19]>>[*:1]-[C;H0;+0:2]1(-[*:3])-[CH;+0:4]=[CH;+0:5]-[*:6]:[*:7]-[O;H0;+0:8]-1.[*:9]-[n+;H0:10]1:[cH;+0:11]:[c;H0;+0:12](-[*:13]):[cH;+0:14]:[cH;+0:15]:[cH;+0:16]:1.[OH2;+0:18].[OH2;+0:19] |
| Reaction |  |
| Core-to-Core | |
| Core-to-Core |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Induction of phytoalexin synthesis in soybean: enzymatic cyclization of prenylated pterocarpans to glyceollin isomers. | Welle R, Grisebach H | 1988 May 15 | 3369863 |
| RHEA:26051 | (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + O2 + reduced [NADPH--hemoprotein reductase] = glyceollin III + H(+) + 2 H2O + oxidized [NADPH--hemoprotein reductase] |
| RULE(radius=1) | ([*:1]-[CH;+0:2]=[C;H0;+0:3](-[*:4])-[CH3;+0:5].[*:6]-[OH;+0:7]).[*:8]-[N;H0;+0:9]1-[CH;+0:10]=[C;H0;+0:11](-[*:12])-[CH2;+0:13]-[CH;+0:14]=[CH;+0:15]-1.[H+;H0:16].[O;H0;+0:17]=[O;H0;+0:18]>>[*:6]-[O;H0;+0:7]-[CH;+0:2](-[*:1])-[C;H0;+0:3](-[*:4])=[CH2;+0:5].[*:8]-[n+;H0:9]1:[cH;+0:10]:[c;H0;+0:11](-[*:12]):[cH;+0:13]:[cH;+0:14]:[cH;+0:15]:1.[OH2;+0:17].[OH2;+0:18] |
| Reaction |  |
| Core-to-Core | |
| Core-to-Core |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Induction of phytoalexin synthesis in soybean: enzymatic cyclization of prenylated pterocarpans to glyceollin isomers. | Welle R, Grisebach H | 1988 May 15 | 3369863 |