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1. Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

ID:	1.14.14.77
Description:	Phenylacetonitrile alpha-monooxygenase.
Alternative Name:	CYP3201B1.

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UniProtKB Enzyme Link:	UniProtKB 1.14.14.77
BRENDA Enzyme Link:	BRENDA 1.14.14.77
KEGG Enzyme Link:	KEGG1.14.14.77
BioCyc Enzyme Link:	BioCyc 1.14.14.77
ExPASy Enzyme Link:	ExPASy1.14.14.77
EC2PDB Enzyme Link:	EC2PDB 1.14.14.77
ExplorEnz Enzyme Link:	ExplorEnz 1.14.14.77
PRIAM enzyme-specific profiles Link:	PRIAM 1.14.14.77
IntEnz Enzyme Link:	IntEnz 1.14.14.77
MEDLINE Enzyme Link:	MEDLINE 1.14.14.77

RHEA:52164	O2 + phenylacetonitrile + reduced [NADPH--hemoprotein reductase] = (R)-mandelonitrile + H(+) + H2O + oxidized [NADPH--hemoprotein reductase]
RULE(radius=1)	[:1]-[CH2;+0:2]-[:3].[:4]-[N;H0;+0:5]1-[:6]:[:7]-[NH;+0:8]-[c;H0;+0:9](:[:10]):[c;H0;+0:11]-1:[nH;+0:12]:[:13].[O;H0;+0:14]=[O;H0;+0:15]>>[:1]-[CH;+0:2](-[:3])-[OH;+0:14].[:4]-[n;H0;+0:5]1:[:6]:[:7]:[n;H0;+0:8]:[c;H0;+0:9](:[:10])-[c;H0;+0:11]:1:[n;H0;+0:12]:[:13].[OH2;+0:15]
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Title	Authors	Date	PubMed ID
Identification and characterization of CYP79D16 and CYP71AN24 catalyzing the first and second steps in L-phenylalanine-derived cyanogenic glycoside biosynthesis in the Japanese apricot, Prunus mume Sieb. et Zucc.	Yamaguchi T, Yamamoto K, Asano Y	2014 Sep	25015725
A novel cytochrome P450, CYP3201B1, is involved in (<i>R</i>)-mandelonitrile biosynthesis in a cyanogenic millipede.	Yamaguchi T, Kuwahara Y, Asano Y	2017 Mar	28286729