Enzyme

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     1. Oxidoreductases
        1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
            1.14.19 With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
ID:1.14.19.11
Description:Acyl-[acyl-carrier-protein] 4-desaturase.
Alternative Name: Delta(4)-palmitoyl-[acyl carrier protein] desaturase.

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 1.14.19.11
BRENDA Enzyme Link: BRENDA 1.14.19.11
KEGG Enzyme Link: KEGG1.14.19.11
BioCyc Enzyme Link: BioCyc 1.14.19.11
ExPASy Enzyme Link: ExPASy1.14.19.11
EC2PDB Enzyme Link: EC2PDB 1.14.19.11
ExplorEnz Enzyme Link: ExplorEnz 1.14.19.11
PRIAM enzyme-specific profiles Link: PRIAM 1.14.19.11
IntEnz Enzyme Link: IntEnz 1.14.19.11
MEDLINE Enzyme Link: MEDLINE 1.14.19.11
MSA:

1.14.19.11;

Phylogenetic Tree:

1.14.19.11;

Uniprot:
M-CSA:
RHEA:38043 2 H(+) + hexadecanoyl-[ACP] + O2 + 2 reduced [2Fe-2S]-[ferredoxin] = (4Z)-hexadecenoyl-[ACP] + 2 H2O + 2 oxidized [2Fe-2S]-[ferredoxin]
RULE(radius=1) [*:1]-[CH2;+0:2]-[CH2;+0:3]-[*:4].[*:5]-[Fe;H0;+0:6]-[*:7].[*:8]-[Fe;H0;+0:9]-[*:10].[H+;H0:11].[H+;H0:12].[O;H0;+0:13]=[O;H0;+0:14]>>[*:1]-[CH;+0:2]=[CH;+0:3]-[*:4].[*:5]-[Fe+;H0:6]-[*:7].[*:8]-[Fe+;H0:9]-[*:10].[OH2;+0:13].[OH2;+0:14]
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References

TitleAuthorsDatePubMed ID
Stearoyl-acyl carrier protein desaturases are associated with floral isolation in sexually deceptive orchids.Schlüter PM, Xu S, Gagliardini V, Whittle E, Shanklin J, Grossniklaus U, Schiestl FP2011 Apr 521436056
A multifunctional acyl-acyl carrier protein desaturase from Hedera helix L. (English ivy) can synthesize 16- and 18-carbon monoene and diene products.Whittle E, Cahoon EB, Subrahmanyam S, Shanklin J2005 Aug 515939740
Expression of a coriander desaturase results in petroselinic acid production in transgenic tobacco.Cahoon EB, Shanklin J, Ohlrogge JB1992 Dec 11454797
Metabolic Evidence for the Involvement of a [delta]4-Palmitoyl-Acyl Carrier Protein Desaturase in Petroselinic Acid Synthesis in Coriander Endosperm and Transgenic Tobacco Cells.Cahoon EB, Ohlrogge JB1994 Mar12232129