Enzyme

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ID:1.14.19.n5
Description:Versicolorin B desaturase.

3D structure

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References

RHEA:35743 H(+) + NADPH + O2 + versicolorin B = 2 H2O + NADP(+) + versicolorin A
RULE(radius=1) [*:1]-[CH2;+0:2]-[CH2;+0:3]-[*:4].[*:5]-[N;H0;+0:6]1-[CH;+0:7]=[C;H0;+0:8](-[*:9])-[CH2;+0:10]-[CH;+0:11]=[CH;+0:12]-1.[H+;H0:13].[O;H0;+0:14]=[O;H0;+0:15]>>[*:1]-[CH;+0:2]=[CH;+0:3]-[*:4].[*:5]-[n+;H0:6]1:[cH;+0:7]:[c;H0;+0:8](-[*:9]):[cH;+0:10]:[cH;+0:11]:[cH;+0:12]:1.[OH2;+0:14].[OH2;+0:15]
Reaction
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References

TitleAuthorsDatePubMed ID
Stereochemistry during aflatoxin biosynthesis: cyclase reaction in the conversion of versiconal to versicolorin B and racemization of versiconal hemiacetal acetate.Yabe K, Hamasaki T1993 Aug8368837