Enzyme

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     3. Hydrolases
        3.1 Acting on ester bonds
            3.1.1 Carboxylic-ester hydrolases
ID:3.1.1.14
Description:Chlorophyllase.

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 3.1.1.14
BRENDA Enzyme Link: BRENDA 3.1.1.14
KEGG Enzyme Link: KEGG3.1.1.14
BioCyc Enzyme Link: BioCyc 3.1.1.14
ExPASy Enzyme Link: ExPASy3.1.1.14
EC2PDB Enzyme Link: EC2PDB 3.1.1.14
ExplorEnz Enzyme Link: ExplorEnz 3.1.1.14
PRIAM enzyme-specific profiles Link: PRIAM 3.1.1.14
IntEnz Enzyme Link: IntEnz 3.1.1.14
MEDLINE Enzyme Link: MEDLINE 3.1.1.14
MSA:

3.1.1.14;

Phylogenetic Tree:

3.1.1.14;

Uniprot:
M-CSA:
RHEA:38011 chlorophyll a + H2O = chlorophyllide a + H(+) + phytol
RULE(radius=1) ([*:1]-[C;H0;+0:2]1=[c;H0;+0:3]2:[*:4]:[*:5]:[c;H0;+0:6]3:[*:7]:2-[*:8]24-[*:9]5:[c;H0;+0:10](:[*:11]:[*:12]:[c;H0;+0:13]:5-[CH;+0:14]=[C;H0;+0:15]5-[*:16]-[*:17]-[C;H0;+0:18]-1=[N+;H0:19]-5-2)-[CH;+0:20]=[C;H0;+0:21]1-[*:22]=[*:23]-[C;H0;+0:24](=[N+;H0:25]-1-4)-[CH;+0:26]=3.[*:27]-[O;H0;+0:28]-[CH2;+0:29]-[*:30]).[OH2;+0:31]>>([*:1]-[C;H0;+0:2]1=[C;H0;+0:18]2-[*:17]-[*:16]-[C;H0;+0:15]3=[N+;H0:19]-2-[*:8]24-[*:9]5:[c;H0;+0:10](:[*:11]:[*:12]:[c;H0;+0:13]:5=[CH;+0:14]-3)=[CH;+0:20]-[C;H0;+0:21]3=[N+;H0:25]-2-[C;H0;+0:24](=[CH;+0:26]-[c;H0;+0:6]2:[*:5]:[*:4]:[c;H0;+0:3]-1:[*:7]:2-4)-[*:23]=[*:22]-3.[*:27]-[OH;+0:28]).[*:30]-[CH2;+0:29]-[OH;+0:31]
Reaction
Core-to-Core More

References

TitleAuthorsDatePubMed ID
Chlorophyll degradation during senescence.Hörtensteiner S200616669755
Characterization and subcellular localization of chlorophyllase from Ginkgo biloba.Okazawa A, Tango L, Itoh Y, Fukusaki E, Kobayashi A2006 Jan-Feb16610227
Cloning of chlorophyllase, the key enzyme in chlorophyll degradation: finding of a lipase motif and the induction by methyl jasmonate.Tsuchiya T, Ohta H, Okawa K, Iwamatsu A, Shimada H, Masuda T, Takamiya K1999 Dec 2110611389

RHEA:19605 a chlorophyll + H2O = a chlorophyllide + H(+) + phytol
RULE(radius=1) [*:1]-[O;H0;+0:2]-[CH2;+0:3]-[*:4].[OH2;+0:5]>>[*:4]-[CH2;+0:3]-[OH;+0:5].[*:1]-[OH;+0:2]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Chlorophyll degradation during senescence.Hörtensteiner S200616669755
Characterization and subcellular localization of chlorophyllase from Ginkgo biloba.Okazawa A, Tango L, Itoh Y, Fukusaki E, Kobayashi A2006 Jan-Feb16610227
Activity and partial purification of chlorophyllase in aqueous systems.KLEIN AO, VISHNIAC W1961 Sep13756631
The breakdown of chlorophyll by chlorophyllase.HOLDEN M1961 Feb13715233
Cloning of chlorophyllase, the key enzyme in chlorophyll degradation: finding of a lipase motif and the induction by methyl jasmonate.Tsuchiya T, Ohta H, Okawa K, Iwamatsu A, Shimada H, Masuda T, Takamiya K1999 Dec 2110611389