Enzyme

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     1. Oxidoreductases
        1.3 Acting on the CH-CH group of donors
            1.3.1 With NAD+ or NADP+ as acceptor
ID:1.3.1.67
Description:dehydrogenase.

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 1.3.1.67
BRENDA Enzyme Link: BRENDA 1.3.1.67
KEGG Enzyme Link: KEGG1.3.1.67
BioCyc Enzyme Link: BioCyc 1.3.1.67
ExPASy Enzyme Link: ExPASy1.3.1.67
EC2PDB Enzyme Link: EC2PDB 1.3.1.67
ExplorEnz Enzyme Link: ExplorEnz 1.3.1.67
PRIAM enzyme-specific profiles Link: PRIAM 1.3.1.67
IntEnz Enzyme Link: IntEnz 1.3.1.67
MEDLINE Enzyme Link: MEDLINE 1.3.1.67
MSA:

1.3.1.67;

Phylogenetic Tree:

1.3.1.67;

Uniprot:
M-CSA:
RHEA:24228 (1R,6S)-1,6-dihydroxy-4-methylcyclohexa-2,4-diene-1-carboxylate + NAD(+) = 4-methylcatechol + CO2 + NADH
RULE(radius=1) [*:1]-[n+;H0:2]1:[cH;+0:3]:[cH;+0:4]:[cH;+0:5]:[c;H0;+0:6](-[*:7]):[cH;+0:8]:1.[*:9]=[C;H0;+0:10](-[OH;+0:11])-[C;H0;+0:12]1(-[*:13])-[CH;+0:14]=[CH;+0:15]-[C;H0;+0:16](-[*:17])=[CH;+0:18]-[CH;+0:19]-1-[*:20]>>[*:1]-[N;H0;+0:2]1-[CH;+0:3]=[CH;+0:4]-[CH2;+0:5]-[C;H0;+0:6](-[*:7])=[CH;+0:8]-1.[*:13]-[c;H0;+0:12]1:[cH;+0:14]:[cH;+0:15]:[c;H0;+0:16](-[*:17]):[cH;+0:18]:[c;H0;+0:19]:1-[*:20].[*:9]=[C;H0;+0:10]=[O;H0;+0:11]
Reaction
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References

TitleAuthorsDatePubMed ID
Identification of cis-diols as intermediates in the oxidation of aromatic acids by a strain of Pseudomonas putida that contains a TOL plasmid.Whited GM, McCombie WR, Kwart LD, Gibson DT1986 Jun3711022

RHEA:24224 (1R,6S)-1,6-dihydroxy-4-methylcyclohexa-2,4-diene-1-carboxylate + NADP(+) = 4-methylcatechol + CO2 + NADPH
RULE(radius=1) [*:1]-[n+;H0:2]1:[cH;+0:3]:[cH;+0:4]:[cH;+0:5]:[c;H0;+0:6](-[*:7]):[cH;+0:8]:1.[*:9]=[C;H0;+0:10](-[OH;+0:11])-[C;H0;+0:12]1(-[*:13])-[CH;+0:14]=[CH;+0:15]-[C;H0;+0:16](-[*:17])=[CH;+0:18]-[CH;+0:19]-1-[*:20]>>[*:1]-[N;H0;+0:2]1-[CH;+0:3]=[CH;+0:4]-[CH2;+0:5]-[C;H0;+0:6](-[*:7])=[CH;+0:8]-1.[*:13]-[c;H0;+0:12]1:[cH;+0:14]:[cH;+0:15]:[c;H0;+0:16](-[*:17]):[cH;+0:18]:[c;H0;+0:19]:1-[*:20].[*:9]=[C;H0;+0:10]=[O;H0;+0:11]
Reaction
Core-to-Core More
Core-to-Core More

References

TitleAuthorsDatePubMed ID
Identification of cis-diols as intermediates in the oxidation of aromatic acids by a strain of Pseudomonas putida that contains a TOL plasmid.Whited GM, McCombie WR, Kwart LD, Gibson DT1986 Jun3711022