EC number:2.2.1.11
Enzyme
Download| EC Tree |
| 2. Transferases |
| 2.2 Transferring aldehyde or ketonic groups |
| 2.2.1 Transketolases and transaldolases |
| ID: | 2.2.1.11 |
|---|---|
| Description: | 6-deoxy-5-ketofructose 1-phosphate synthase. |
| Alternative Name: |
DKFP synthase. |
3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 2.2.1.11 |
| BRENDA Enzyme Link: | BRENDA 2.2.1.11 |
| KEGG Enzyme Link: | KEGG2.2.1.11 |
| BioCyc Enzyme Link: | BioCyc 2.2.1.11 |
| ExPASy Enzyme Link: | ExPASy2.2.1.11 |
| EC2PDB Enzyme Link: | EC2PDB 2.2.1.11 |
| ExplorEnz Enzyme Link: | ExplorEnz 2.2.1.11 |
| PRIAM enzyme-specific profiles Link: | PRIAM 2.2.1.11 |
| IntEnz Enzyme Link: | IntEnz 2.2.1.11 |
| MEDLINE Enzyme Link: | MEDLINE 2.2.1.11 |
| RHEA:32259 | beta-D-fructose 1-phosphate + methylglyoxal = 1-deoxy-D-threo-hexo-2,5-diulose 6-phosphate + D-glyceraldehyde |
| RULE(radius=1) | [*:1]-[CH;+0:2]1-[CH;+0:3](-[OH;+0:4])-[*:5]-[O;H0;+0:6]-[C;H0;+0:7]-1(-[*:8])-[OH;+0:9].[*:10]-[CH;+0:11]=[O;H0;+0:12]>>[*:1]-[CH;+0:2](-[C;H0;+0:7](-[*:8])=[O;H0;+0:9])-[CH;+0:11](-[*:10])-[OH;+0:12].[O;H0;+0:4]=[CH;+0:3]-[*:5]-[OH;+0:6] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Methylglyoxal is an intermediate in the biosynthesis of 6-deoxy-5-ketofructose-1-phosphate: a precursor for aromatic amino acid biosynthesis in Methanocaldococcus jannaschii. | White RH, Xu H | 2006 Oct 10 | 17014089 |
| MJ0400 from Methanocaldococcus jannaschii exhibits fructose-1,6-bisphosphate aldolase activity. | Samland AK, Wang M, Sprenger GA | 2008 Apr | 18318840 |
| RHEA:31911 | beta-D-fructose 1,6-bisphosphate + methylglyoxal = 1-deoxy-D-threo-hexo-2,5-diulose 6-phosphate + D-glyceraldehyde 3-phosphate |
| RULE(radius=1) | [*:1]-[C;H0;+0:2]1(-[OH;+0:3])-[O;H0;+0:4]-[*:5]-[CH;+0:6](-[OH;+0:7])-[CH;+0:8]-1-[*:9].[*:10]-[CH;+0:11]=[O;H0;+0:12]>>[*:1]-[C;H0;+0:2](=[O;H0;+0:3])-[CH;+0:8](-[*:9])-[CH;+0:11](-[*:10])-[OH;+0:12].[O;H0;+0:7]=[CH;+0:6]-[*:5]-[OH;+0:4] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Methylglyoxal is an intermediate in the biosynthesis of 6-deoxy-5-ketofructose-1-phosphate: a precursor for aromatic amino acid biosynthesis in Methanocaldococcus jannaschii. | White RH, Xu H | 2006 Oct 10 | 17014089 |
| MJ0400 from Methanocaldococcus jannaschii exhibits fructose-1,6-bisphosphate aldolase activity. | Samland AK, Wang M, Sprenger GA | 2008 Apr | 18318840 |