EC number:2.3.1.156

Enzyme

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     2. Transferases
        2.3 Acyltransferases
            2.3.1 Transferring groups other than aminoacyl groups
ID:2.3.1.156
Description:Phloroisovalerophenone synthase.
Alternative Name: Valerophenone synthase.
3-methyl-1-(trihydroxyphenyl)butan-1-one synthase.
Prosite: PDOC00403;
PDB:
PDBScop

3D structure

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PDB

References

External Links

UniProtKB Enzyme Link: UniProtKB 2.3.1.156
BRENDA Enzyme Link: BRENDA 2.3.1.156
KEGG Enzyme Link: KEGG2.3.1.156
BioCyc Enzyme Link: BioCyc 2.3.1.156
ExPASy Enzyme Link: ExPASy2.3.1.156
EC2PDB Enzyme Link: EC2PDB 2.3.1.156
ExplorEnz Enzyme Link: ExplorEnz 2.3.1.156
PRIAM enzyme-specific profiles Link: PRIAM 2.3.1.156
IntEnz Enzyme Link: IntEnz 2.3.1.156
MEDLINE Enzyme Link: MEDLINE 2.3.1.156

EC number:2.3.1.156

MSA:

2.3.1.156;
Phylogenetic Tree:

2.3.1.156;
Uniprot:
M-CSA:
RHEA:23572 3-methylbutanoyl-CoA + 3 H(+) + 3 malonyl-CoA = 3 CO2 + 4 CoA + phlorisovalerophenone
RULE(radius=1) [C:0][S;H0:1][C:2](=[O:3])[*:4].[C:5][S;H0:6][C:7](=[O:8])[C:9][C:10](=[O:11])[O:12].[C:13][S;H0:14][C:15](=[O:16])[C:17][C:18](=[O:19])[O:20].[C:21][S;H0:22][C:23](=[O:24])[C:25][C:26](=[O:27])[O:28]>>[OH:24][c:23]1[c:25][c:7]([OH:8])[c:9][c:15]([OH:16])[c:17]1[C:2](=[O:3])[*:4].[O:11]=[C:10]=[O:12].[O:19]=[C:18]=[O:20].[O:27]=[C:26]=[O:28].[C:5][SH:6].[C:13][SH:14].[C:21][SH:22].[C:0][SH:1]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
4-Hydroxy-2-pyrone formation by chalcone and stilbene synthase with nonphysiological substrates.Zuurbier KW, Leser J, Berger T, Hofte AJ, Schröder G, Verpoorte R, Schröder J1998 Dec9883590
Phlorisovalerophenone synthase, a novel polyketide synthase from hop (Humulus lupulus L.) cones.Paniego NB, Zuurbier KW, Fung SY, van der Heijden R, Scheffer JJ, Verpoorte R1999 Jun10336650