Enzyme

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     2. Transferases
        2.5 Transferring alkyl or aryl groups, other than methyl groups
            2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
ID:2.5.1.124
Description:6-linalyl-2-O,3-dimethylflaviolin synthase.
Alternative Name: methylnaphthalene-1,4-dione synthase.
6-(3,7-dimethylocta-1,6-dien-3-yl)-5,7-dihydroxy-2-methoxy-3-

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 2.5.1.124
BRENDA Enzyme Link: BRENDA 2.5.1.124
KEGG Enzyme Link: KEGG2.5.1.124
BioCyc Enzyme Link: BioCyc 2.5.1.124
ExPASy Enzyme Link: ExPASy2.5.1.124
EC2PDB Enzyme Link: EC2PDB 2.5.1.124
ExplorEnz Enzyme Link: ExplorEnz 2.5.1.124
PRIAM enzyme-specific profiles Link: PRIAM 2.5.1.124
IntEnz Enzyme Link: IntEnz 2.5.1.124
MEDLINE Enzyme Link: MEDLINE 2.5.1.124
MSA:

2.5.1.124;

Phylogenetic Tree:

2.5.1.124;

Uniprot:
M-CSA:
RHEA:41007 (2E)-geranyl diphosphate + 2-O,3-dimethylflaviolin = 6-linalyl-2-O,3-dimethylflaviolin + diphosphate
RULE(radius=1) [*:1]-[C;H0;+0:2](-[*:3])=[CH;+0:4]-[CH2;+0:5]-[O;H0;+0:6]-[*:7].[*:8]:[cH;+0:9]:[*:10]>>[*:1]-[C;H0;+0:2](-[*:3])(-[CH;+0:4]=[CH2;+0:5])-[c;H0;+0:9](:[*:8]):[*:10].[*:7]-[OH;+0:6]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Functional characterization of the promiscuous prenyltransferase responsible for furaquinocin biosynthesis: identification of a physiological polyketide substrate and its prenylated reaction products.Kumano T, Tomita T, Nishiyama M, Kuzuyama T2010 Dec 1720937800