Enzyme

Download
EC Tree
     2. Transferases
        2.5 Transferring alkyl or aryl groups, other than methyl groups
            2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
ID:2.5.1.36
Description:Trihydroxypterocarpan dimethylallyltransferase.
Alternative Name: Glyceollin synthase.
transferase.
Dimethylallylpyrophosphate:trihydroxypterocarpan dimethylallyl
dimethylallyltransferase.
Dimethylallylpyrophosphate:3,6a,9-trihydroxypterocarpan
dimethyltransferase.
Dimethylallyl-diphosphate:(6aS,11aS)-3,6a,9-trihydroxypterocarpan

3D structure

Click one PDB to see exact 3D structure provided by NGL.

Note: Use your mouse to drag, rotate, and zoom in and out of the structure. Mouse-over to identify atoms and bonds. Mouse controls documentation.

References

External Links

UniProtKB Enzyme Link: UniProtKB 2.5.1.36
BRENDA Enzyme Link: BRENDA 2.5.1.36
KEGG Enzyme Link: KEGG2.5.1.36
BioCyc Enzyme Link: BioCyc 2.5.1.36
ExPASy Enzyme Link: ExPASy2.5.1.36
EC2PDB Enzyme Link: EC2PDB 2.5.1.36
ExplorEnz Enzyme Link: ExplorEnz 2.5.1.36
PRIAM enzyme-specific profiles Link: PRIAM 2.5.1.36
IntEnz Enzyme Link: IntEnz 2.5.1.36
MEDLINE Enzyme Link: MEDLINE 2.5.1.36
MSA:

2.5.1.36;

Phylogenetic Tree:

2.5.1.36;

Uniprot:
M-CSA:
RHEA:23184 (6aS,11aS)-3,6a,9-trihydroxypterocarpan + dimethylallyl diphosphate = (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan + diphosphate
RULE(radius=1) [*:1]-[O;H0;+0:2]-[CH2;+0:3]-[*:4].[*:5]:[cH;+0:6]:[*:7]>>[*:1]-[OH;+0:2].[*:5]:[c;H0;+0:6](:[*:7])-[CH2;+0:3]-[*:4]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Molecular cloning and characterization of a cDNA for pterocarpan 4-dimethylallyltransferase catalyzing the key prenylation step in the biosynthesis of glyceollin, a soybean phytoalexin.Akashi T, Sasaki K, Aoki T, Ayabe S, Yazaki K2009 Feb19091879

RHEA:19345 (6aS,11aS)-3,6a,9-trihydroxypterocarpan + dimethylallyl diphosphate = (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + diphosphate
RULE(radius=1) [*:1]-[O;H0;+0:2]-[CH2;+0:3]-[*:4].[*:5]:[cH;+0:6]:[*:7]>>[*:1]-[OH;+0:2].[*:5]:[c;H0;+0:6](:[*:7])-[CH2;+0:3]-[*:4]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Molecular cloning and characterization of a cDNA for pterocarpan 4-dimethylallyltransferase catalyzing the key prenylation step in the biosynthesis of glyceollin, a soybean phytoalexin.Akashi T, Sasaki K, Aoki T, Ayabe S, Yazaki K2009 Feb19091879