EC number:3.1.1.80
| ID: | 3.1.1.80 |
|---|---|
| Description: | Acetylajmaline esterase. |
| Alternative Name: |
Acetylajmalan esterase. AAE. 2-beta-(R)-17-O-acetylajmalan:acetylesterase. |
3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 3.1.1.80 |
| BRENDA Enzyme Link: | BRENDA 3.1.1.80 |
| KEGG Enzyme Link: | KEGG3.1.1.80 |
| BioCyc Enzyme Link: | BioCyc 3.1.1.80 |
| ExPASy Enzyme Link: | ExPASy3.1.1.80 |
| EC2PDB Enzyme Link: | EC2PDB 3.1.1.80 |
| ExplorEnz Enzyme Link: | ExplorEnz 3.1.1.80 |
| PRIAM enzyme-specific profiles Link: | PRIAM 3.1.1.80 |
| IntEnz Enzyme Link: | IntEnz 3.1.1.80 |
| MEDLINE Enzyme Link: | MEDLINE 3.1.1.80 |
| RHEA:23796 | 17-O-acetylnorajmaline + H2O = acetate + H(+) + norajmaline |
| RULE(radius=1) | [*:1]=[C;H0;+0:2](-[*:3])-[O;H0;+0:4]-[*:5].[OH2;+0:6]>>[*:5]-[OH;+0:4].[*:1]=[C;H0;+0:2](-[*:3])-[OH;+0:6] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Functional expression of an ajmaline pathway-specific esterase from Rauvolfia in a novel plant-virus expression system. | Ruppert M, Woll J, Giritch A, Genady E, Ma X, Stöckigt J | 2005 Nov | 16133216 |
| Characterization of 2 beta (R)-17-O-acetylajmalan: acetylesterase--a specific enzyme involved in the biosynthesis of the Rauwolfia alkaloid ajmaline. | Polz L, Schübel H, Stöckigt J | 1987 Apr | 2955586 |
| RHEA:22124 | 17-O-acetylajmaline + H2O = acetate + ajmaline + H(+) |
| RULE(radius=1) | [*:1]=[C;H0;+0:2](-[*:3])-[O;H0;+0:4]-[*:5].[OH2;+0:6]>>[*:5]-[OH;+0:4].[*:1]=[C;H0;+0:2](-[*:3])-[OH;+0:6] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Functional expression of an ajmaline pathway-specific esterase from Rauvolfia in a novel plant-virus expression system. | Ruppert M, Woll J, Giritch A, Genady E, Ma X, Stöckigt J | 2005 Nov | 16133216 |
| Characterization of 2 beta (R)-17-O-acetylajmalan: acetylesterase--a specific enzyme involved in the biosynthesis of the Rauwolfia alkaloid ajmaline. | Polz L, Schübel H, Stöckigt J | 1987 Apr | 2955586 |