EC number:3.1.1.83
| ID: | 3.1.1.83 | ||
|---|---|---|---|
| Description: | Monoterpene epsilon-lactone hydrolase. | ||
| Alternative Name: |
MLH. | ||
| Prosite: | PDOC00903; | ||
| PDB: |
|
3D structure
Click one PDB to see exact 3D structure provided by NGL.
Note: Use your mouse to drag, rotate, and zoom in and out of the structure. Mouse-over to identify atoms and bonds. Mouse controls documentation.References
External Links
| UniProtKB Enzyme Link: | UniProtKB 3.1.1.83 |
| BRENDA Enzyme Link: | BRENDA 3.1.1.83 |
| KEGG Enzyme Link: | KEGG3.1.1.83 |
| BioCyc Enzyme Link: | BioCyc 3.1.1.83 |
| ExPASy Enzyme Link: | ExPASy3.1.1.83 |
| EC2PDB Enzyme Link: | EC2PDB 3.1.1.83 |
| ExplorEnz Enzyme Link: | ExplorEnz 3.1.1.83 |
| PRIAM enzyme-specific profiles Link: | PRIAM 3.1.1.83 |
| IntEnz Enzyme Link: | IntEnz 3.1.1.83 |
| MEDLINE Enzyme Link: | MEDLINE 3.1.1.83 |
| RHEA:32507 | 4-isopropenyl-7-methyloxepan-2-one + H2O = 6-hydroxy-3-isopropenylheptanoate + H(+) |
| RULE(radius=1) | [*:1]-[O;H0;+0:2]-[C;H0;+0:4](=[*:3])-[*:5].[OH2;+0:6]>>([*:1]-[OH;+0:2].[*:3]=[C;H0;+0:4](-[*:5])-[OH;+0:6]).[H+;H0:7] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Genetic and biochemical characterization of a novel monoterpene epsilon-lactone hydrolase from Rhodococcus erythropolis DCL14. | van der Vlugt-Bergmans CJ, van der Werf MJ | 2001 Feb | 11157238 |
| RHEA:32511 | (4R,7R)-4-isopropenyl-7-methyloxepan-2-one + H2O = (3R,6R)-6-hydroxy-3-isopropenylheptanoate + H(+) |
| RULE(radius=1) | [*:1]-[O;H0;+0:2]-[C;H0;+0:4](=[*:3])-[*:5].[OH2;+0:6]>>([*:1]-[OH;+0:2].[*:3]=[C;H0;+0:4](-[*:5])-[OH;+0:6]).[H+;H0:7] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Genetic and biochemical characterization of a novel monoterpene epsilon-lactone hydrolase from Rhodococcus erythropolis DCL14. | van der Vlugt-Bergmans CJ, van der Werf MJ | 2001 Feb | 11157238 |
| RHEA:32515 | (4S,7R)-4-isopropenyl-7-methyloxepan-2-one + H2O = (3S,6R)-6-hydroxy-3-isopropenylheptanoate + H(+) |
| RULE(radius=1) | [*:1]-[O;H0;+0:2]-[C;H0;+0:4](=[*:3])-[*:5].[OH2;+0:6]>>([*:1]-[OH;+0:2].[*:3]=[C;H0;+0:4](-[*:5])-[OH;+0:6]).[H+;H0:7] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Genetic and biochemical characterization of a novel monoterpene epsilon-lactone hydrolase from Rhodococcus erythropolis DCL14. | van der Vlugt-Bergmans CJ, van der Werf MJ | 2001 Feb | 11157238 |
| RHEA:32591 | (4R,7S)-7-isopropyl-4-methyloxepan-2-one + H2O = (3R,6S)-6-hydroxy-3,7-dimethyloctanoate + H(+) |
| RULE(radius=1) | [*:1]-[O;H0;+0:2]-[C;H0;+0:4](=[*:3])-[*:5].[OH2;+0:6]>>([*:1]-[OH;+0:2].[*:3]=[C;H0;+0:4](-[*:5])-[OH;+0:6]).[H+;H0:7] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Genetic and biochemical characterization of a novel monoterpene epsilon-lactone hydrolase from Rhodococcus erythropolis DCL14. | van der Vlugt-Bergmans CJ, van der Werf MJ | 2001 Feb | 11157238 |
| RHEA:32595 | 7-isopropyl-4-methyloxepan-2-one + H2O = 6-hydroxy-3,7-dimethyloctanoate + H(+) |
| RULE(radius=1) | [*:1]-[O;H0;+0:2]-[C;H0;+0:4](=[*:3])-[*:5].[OH2;+0:6]>>([*:1]-[OH;+0:2].[*:3]=[C;H0;+0:4](-[*:5])-[OH;+0:6]).[H+;H0:7] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Genetic and biochemical characterization of a novel monoterpene epsilon-lactone hydrolase from Rhodococcus erythropolis DCL14. | van der Vlugt-Bergmans CJ, van der Werf MJ | 2001 Feb | 11157238 |