EC number:4.1.1.77
| ID: | 4.1.1.77 |
|---|---|
| Description: | 2-oxo-3-hexenedioate decarboxylase. |
| Alternative Name: |
4-oxalocrotonate decarboxylase. 4-oxalocrotonate carboxy-lyase. |
| Cath: | 3.90.850.10; |
3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 4.1.1.77 |
| BRENDA Enzyme Link: | BRENDA 4.1.1.77 |
| KEGG Enzyme Link: | KEGG4.1.1.77 |
| BioCyc Enzyme Link: | BioCyc 4.1.1.77 |
| ExPASy Enzyme Link: | ExPASy4.1.1.77 |
| EC2PDB Enzyme Link: | EC2PDB 4.1.1.77 |
| ExplorEnz Enzyme Link: | ExplorEnz 4.1.1.77 |
| PRIAM enzyme-specific profiles Link: | PRIAM 4.1.1.77 |
| IntEnz Enzyme Link: | IntEnz 4.1.1.77 |
| MEDLINE Enzyme Link: | MEDLINE 4.1.1.77 |
| RHEA:24260 | (3E)-2-oxohex-3-enedioate + H(+) = 2-oxopent-4-enoate + CO2 |
| RULE(radius=1) | [*:1]=[C;H0;+0:2](-[OH;+0:3])-[CH2;+0:4]-[CH;+0:5]=[CH;+0:6]-[*:7].[H+;H0:8]>>[*:7]-[CH2;+0:6]-[CH;+0:5]=[CH2;+0:4].[*:1]=[C;H0;+0:2]=[O;H0;+0:3] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Uncovering the protocatechuate 2,3-cleavage pathway genes. | Kasai D, Fujinami T, Abe T, Mase K, Katayama Y, Fukuda M, Masai E | 2009 Nov | 19717587 |
| Complete nucleotide sequence and functional analysis of the genes for 2-aminophenol metabolism from Pseudomonas sp. AP-3. | Takenaka S, Murakami S, Kim YJ, Aoki K | 2000 Oct | 11081795 |
| Metabolism of 2-aminophenol by Pseudomonas sp. AP-3: modified meta-cleavage pathway. | Takenaka S, Murakami S, Shinke R, Aoki K | 1998 Aug | 9683650 |
| Kinetic and stereochemical analysis of YwhB, a 4-oxalocrotonate tautomerase homologue in Bacillus subtilis: mechanistic implications for the YwhB- and 4-oxalocrotonate tautomerase-catalyzed reactions. | Wang SC, Johnson WH Jr, Czerwinski RM, Stamps SL, Whitman CP | 2007 Oct 23 | 17902707 |
| Nucleotide sequence and functional analysis of the complete phenol/3,4-dimethylphenol catabolic pathway of Pseudomonas sp. strain CF600. | Shingler V, Powlowski J, Marklund U | 1992 Feb | 1732207 |
| Expression and stereochemical and isotope effect studies of active 4-oxalocrotonate decarboxylase. | Stanley TM, Johnson WH Jr, Burks EA, Whitman CP, Hwang CC, Cook PF | 2000 Feb 1 | 10651637 |