Enzyme

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     4. Lyases
        4.2 Carbon-oxygen lyases
            4.2.1 Hydro-lyases
ID:4.2.1.83
Description:4-oxalmesaconate hydratase.
Alternative Name: 4-carboxy-2-oxohexenedioate hydratase.
Cath: 3.40.50.10320;

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 4.2.1.83
BRENDA Enzyme Link: BRENDA 4.2.1.83
KEGG Enzyme Link: KEGG4.2.1.83
BioCyc Enzyme Link: BioCyc 4.2.1.83
ExPASy Enzyme Link: ExPASy4.2.1.83
EC2PDB Enzyme Link: EC2PDB 4.2.1.83
ExplorEnz Enzyme Link: ExplorEnz 4.2.1.83
PRIAM enzyme-specific profiles Link: PRIAM 4.2.1.83
IntEnz Enzyme Link: IntEnz 4.2.1.83
MEDLINE Enzyme Link: MEDLINE 4.2.1.83
MSA:

4.2.1.83;

Phylogenetic Tree:

4.2.1.83;

Uniprot:
M-CSA:
RHEA:17401 2-hydroxy-4-oxobutane-1,2,4-tricarboxylate = 4-carboxy-2-hydroxy-cis,cis-muconate + H2O
RULE(radius=1) [*:1]-[CH2;+0:2]-[C;H0;+0:3](-[*:4])(-[OH;+0:5])-[CH2;+0:6]-[C;H0;+0:7](-[*:8])=[O;H0;+0:9]>>[*:1]-[CH;+0:2]=[C;H0;+0:3](-[*:4])-[CH;+0:6]=[C;H0;+0:7](-[*:8])-[OH;+0:9].[OH2;+0:5]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Enzymes responsible for degradation of 4-oxalmesaconic acid in Pseudomonas ochraceae.Maruyama K1983 Feb6841354
Purification and properties of gamma-oxalomesaconate hydratase from Pseudomonas ochraceae grown with phthalate.Maruyama K1985 Apr 163985968
The 4-oxalomesaconate hydratase gene, involved in the protocatechuate 4,5-cleavage pathway, is essential to vanillate and syringate degradation in Sphingomonas paucimobilis SYK-6.Hara H, Masai E, Katayama Y, Fukuda M2000 Dec11092855
Unravelling the gallic acid degradation pathway in bacteria: the gal cluster from Pseudomonas putida.Nogales J, Canales A, Jiménez-Barbero J, Serra B, Pingarrón JM, García JL, Díaz E2011 Jan21219457