Enzyme

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     4. Lyases
        4.2 Carbon-oxygen lyases
            4.2.1 Hydro-lyases
ID:4.2.1.92
Description:Hydroperoxide dehydratase.
Alternative Name: Hydroperoxide isomerase.
AOS.
Allene oxide synthase.
Prosite: PDOC00081;
PDB:
PDBScop
Cath: 1.10.630.10; 1.20.245.10; 3.10.450.60; 2.40.180.10; 2.40.480.10; 2.60.60.20;

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 4.2.1.92
BRENDA Enzyme Link: BRENDA 4.2.1.92
KEGG Enzyme Link: KEGG4.2.1.92
BioCyc Enzyme Link: BioCyc 4.2.1.92
ExPASy Enzyme Link: ExPASy4.2.1.92
EC2PDB Enzyme Link: EC2PDB 4.2.1.92
ExplorEnz Enzyme Link: ExplorEnz 4.2.1.92
PRIAM enzyme-specific profiles Link: PRIAM 4.2.1.92
IntEnz Enzyme Link: IntEnz 4.2.1.92
MEDLINE Enzyme Link: MEDLINE 4.2.1.92
MSA:

4.2.1.92;

Phylogenetic Tree:

4.2.1.92;

Uniprot:
M-CSA:
RHEA:25074 (13S)-hydroperoxy-(9Z,11E,15Z)-octadecatrienoate = (9Z,13S,15Z)-12,13-epoxyoctadeca-9,11,15-trienoate + H2O
RULE(radius=1) [*:1]=[CH;+0:2]-[*:3]-[O;H0;+0:4]-[OH;+0:5]>>[*:1]=[C;H0;+0:2]1-[*:3]-[O;H0;+0:4]-1.[OH2;+0:5]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Cloning, molecular and functional characterization of Arabidopsis thaliana allene oxide synthase (CYP 74), the first enzyme of the octadecanoid pathway to jasmonates.Laudert D, Pfannschmidt U, Lottspeich F, Holländer-Czytko H, Weiler EW1996 May8756596
Biosynthesis of 12-oxo-10,15(Z)-phytodienoic acid: identification of an allene oxide cyclase.Hamberg M1988 Oct 143178850