EC number:4.2.3.10
| ID: | 4.2.3.10 |
|---|---|
| Description: | (-)-endo-fenchol synthase. |
3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 4.2.3.10 |
| BRENDA Enzyme Link: | BRENDA 4.2.3.10 |
| KEGG Enzyme Link: | KEGG4.2.3.10 |
| BioCyc Enzyme Link: | BioCyc 4.2.3.10 |
| ExPASy Enzyme Link: | ExPASy4.2.3.10 |
| EC2PDB Enzyme Link: | EC2PDB 4.2.3.10 |
| ExplorEnz Enzyme Link: | ExplorEnz 4.2.3.10 |
| PRIAM enzyme-specific profiles Link: | PRIAM 4.2.3.10 |
| IntEnz Enzyme Link: | IntEnz 4.2.3.10 |
| MEDLINE Enzyme Link: | MEDLINE 4.2.3.10 |
| RHEA:20565 | (2E)-geranyl diphosphate + H2O = (1S,2S,4R)-endo-fenchol + diphosphate |
| RULE(radius=1) | [*:1]-[C;H0;+0:2](-[*:3]-[*:4]-[CH;+0:5]=[C;H0;+0:6](-[*:7])-[*:8])=[CH;+0:9]-[CH2;+0:10]-[O;H0;+0:11]-[P;H0;+0:12](-[*:13])(=[*:14])-[*:15].[OH2;+0:16]>>[*:1]-[C;H0;+0:2]12-[*:3]-[*:4]-[CH;+0:5](-[CH2;+0:9]-1)-[C;H0;+0:6](-[*:7])(-[*:8])-[CH;+0:10]-2-[OH;+0:11].[*:13]-[P;H0;+0:12](=[*:14])(-[*:15])-[OH;+0:16] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Biosynthesis of monoterpenes. Stereochemistry of the enzymatic cyclization of geranyl pyrophosphate to (-)-endo-fenchol. | Croteau R, Satterwhite DM, Wheeler CJ, Felton NM | 1988 Oct 25 | 3170591 |
| Monoterpene biosynthesis: mechanistic evaluation of the geranyl pyrophosphate:(-)-endo-fenchol cyclase from fennel (Foeniculum vulgare). | Croteau R, Miyazaki JH, Wheeler CJ | 1989 Mar | 2919880 |
| The biochemical and molecular basis for the divergent patterns in the biosynthesis of terpenes and phenylpropenes in the peltate glands of three cultivars of basil. | Iijima Y, Davidovich-Rikanati R, Fridman E, Gang DR, Bar E, Lewinsohn E, Pichersky E | 2004 Nov | 15516500 |