EC number:4.2.3.11
| ID: | 4.2.3.11 |
|---|---|
| Description: | Sabinene-hydrate synthase. |
| Alternative Name: |
Sabinene hydrate cyclase. |
3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 4.2.3.11 |
| BRENDA Enzyme Link: | BRENDA 4.2.3.11 |
| KEGG Enzyme Link: | KEGG4.2.3.11 |
| BioCyc Enzyme Link: | BioCyc 4.2.3.11 |
| ExPASy Enzyme Link: | ExPASy4.2.3.11 |
| EC2PDB Enzyme Link: | EC2PDB 4.2.3.11 |
| ExplorEnz Enzyme Link: | ExplorEnz 4.2.3.11 |
| PRIAM enzyme-specific profiles Link: | PRIAM 4.2.3.11 |
| IntEnz Enzyme Link: | IntEnz 4.2.3.11 |
| MEDLINE Enzyme Link: | MEDLINE 4.2.3.11 |
| RHEA:19565 | (2E)-geranyl diphosphate + H2O = diphosphate + sabinene hydrate |
| RULE(radius=1) | [*:1]-[C;H0;+0:2](-[*:3]-[*:4]-[CH;+0:5]=[C;H0;+0:6](-[*:7])-[*:8])=[CH;+0:9]-[CH2;+0:10]-[O;H0;+0:11]-[*:12].[OH2;+0:13]>>[*:1]-[C;H0;+0:2]1(-[OH;+0:13])-[*:3]-[*:4]-[C;H0;+0:5]2(-[CH;+0:6](-[*:7])-[*:8])-[CH2;+0:10]-[CH;+0:9]-1-2.[*:12]-[OH;+0:11] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Monoterpene biosynthesis: demonstration of a geranyl pyrophosphate:sabinene hydrate cyclase in soluble enzyme preparations from sweet marjoram (Majorana hortensis). | Hallahan TW, Croteau R | 1988 Aug 1 | 3401015 |
| Monoterpene biosynthesis: mechanism and stereochemistry of the enzymatic cyclization of geranyl pyrophosphate to (+)-cis- and (+)-trans-sabinene hydrate. | Hallahan TW, Croteau R | 1989 Feb 15 | 2916845 |