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4. Lyases

4.2 Carbon-oxygen lyases

4.2.3 Acting on phosphates

ID:	4.2.3.176
Description:	Sesterfisherol synthase.

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UniProtKB Enzyme Link:	UniProtKB 4.2.3.176
BRENDA Enzyme Link:	BRENDA 4.2.3.176
KEGG Enzyme Link:	KEGG4.2.3.176
BioCyc Enzyme Link:	BioCyc 4.2.3.176
ExPASy Enzyme Link:	ExPASy4.2.3.176
EC2PDB Enzyme Link:	EC2PDB 4.2.3.176
ExplorEnz Enzyme Link:	ExplorEnz 4.2.3.176
PRIAM enzyme-specific profiles Link:	PRIAM 4.2.3.176
IntEnz Enzyme Link:	IntEnz 4.2.3.176
MEDLINE Enzyme Link:	MEDLINE 4.2.3.176

RHEA:54068	(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O = diphosphate + sesterfisherol
RULE(radius=1)	[:1]-[C;H0;+0:2](-[:3]-[:4]-[CH;+0:5]=[C;H0;+0:6](-[:7])-[:8]-[:9]-[CH;+0:10]=[:11]-[CH2;+0:12]-[:13]-[CH;+0:14]=[C;H0;+0:15](-[:16])-[:17]-[:18]-[CH;+0:19]=[C;H0;+0:20](-[:21])-[:22])=[CH;+0:23]-[CH2;+0:24]-[O;H0;+0:25]-[:26].[OH2;+0:27]>>[:1]-[CH;+0:2]1-[:3]-[:4]-[CH;+0:5]2-[C;H0;+0:10](=[:11]-[C;H0;+0:12]3(-[OH;+0:27])-[:13]-[CH;+0:14]4-[CH;+0:19](-[CH;+0:20](-[:21])-[:22])-[:18]-[:17]-[C;H0;+0:15]-4(-[:16])-[CH2;+0:24]-[CH;+0:23]-1-3)-[:9]-[:8]-[CH;+0:6]-2-[:7].[:26]-[OH;+0:25]
Reaction
Core-to-Core	No scaffolds atoms were exchanged as a result of the reaction

Title	Authors	Date	PubMed ID
Genome Mining for Sesterterpenes Using Bifunctional Terpene Synthases Reveals a Unified Intermediate of Di/Sesterterpenes.	Ye Y, Minami A, Mandi A, Liu C, Taniguchi T, Kuzuyama T, Monde K, Gomi K, Oikawa H	2015 Sep 16	26332841