Enzyme

Download
EC Tree
     4. Lyases
        4.2 Carbon-oxygen lyases
            4.2.3 Acting on phosphates
ID:4.2.3.195
Description:Rhizathalene A synthase.

3D structure

Click one PDB to see exact 3D structure provided by NGL.

Note: Use your mouse to drag, rotate, and zoom in and out of the structure. Mouse-over to identify atoms and bonds. Mouse controls documentation.

References

External Links

UniProtKB Enzyme Link: UniProtKB 4.2.3.195
BRENDA Enzyme Link: BRENDA 4.2.3.195
KEGG Enzyme Link: KEGG4.2.3.195
BioCyc Enzyme Link: BioCyc 4.2.3.195
ExPASy Enzyme Link: ExPASy4.2.3.195
EC2PDB Enzyme Link: EC2PDB 4.2.3.195
ExplorEnz Enzyme Link: ExplorEnz 4.2.3.195
PRIAM enzyme-specific profiles Link: PRIAM 4.2.3.195
IntEnz Enzyme Link: IntEnz 4.2.3.195
MEDLINE Enzyme Link: MEDLINE 4.2.3.195
MSA:

4.2.3.195;

Phylogenetic Tree:

4.2.3.195;

Uniprot:
M-CSA:
RHEA:55216 all-trans-geranylgeranyl diphosphate = diphosphate + rhizathalene A
RULE(radius=1) [*:1]-[C;H0;+0:2](-[*:3]-[*:4]-[CH;+0:5]=[C;H0;+0:6](-[*:7])-[CH3;+0:8])=[CH;+0:9]-[*:10]-[CH2;+0:11]-[C;H0;+0:12](-[CH3;+0:13])=[CH;+0:14]-[*:15]-[CH2;+0:16]-[C;H0;+0:17](-[CH3;+0:18])=[CH;+0:19]-[CH2;+0:20]-[O;H0;+0:21]-[*:22]>>[*:1]-[C;H0;+0:2]12-[*:3]-[*:4]-[CH;+0:5](-[C;H0;+0:6](-[*:7])=[CH2;+0:8])-[CH;+0:13]-1-[C;H0;+0:12]1(-[CH2;+0:18]-[CH;+0:17]=[C;H0;+0:16](-[CH3;+0:19])-[*:15]-[CH2;+0:14]-1)-[CH;+0:11](-[CH3;+0:20])-[*:10]-[CH2;+0:9]-2.[*:22]-[OH;+0:21]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Formation of the unusual semivolatile diterpene rhizathalene by the Arabidopsis class I terpene synthase TPS08 in the root stele is involved in defense against belowground herbivory.Vaughan MM, Wang Q, Webster FX, Kiemle D, Hong YJ, Tantillo DJ, Coates RM, Wray AT, Askew W, O'Donnell C, Tokuhisa JG, Tholl D2013 Mar23512856