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4. Lyases

4.2 Carbon-oxygen lyases

4.2.3 Acting on phosphates

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UniProtKB Enzyme Link:	UniProtKB 4.2.3.27
BRENDA Enzyme Link:	BRENDA 4.2.3.27
KEGG Enzyme Link:	KEGG4.2.3.27
BioCyc Enzyme Link:	BioCyc 4.2.3.27
ExPASy Enzyme Link:	ExPASy4.2.3.27
EC2PDB Enzyme Link:	EC2PDB 4.2.3.27
ExplorEnz Enzyme Link:	ExplorEnz 4.2.3.27
PRIAM enzyme-specific profiles Link:	PRIAM 4.2.3.27
IntEnz Enzyme Link:	IntEnz 4.2.3.27
MEDLINE Enzyme Link:	MEDLINE 4.2.3.27

RHEA:13369	dimethylallyl diphosphate = diphosphate + isoprene
RULE(radius=1)	[:1]-[C;H0;+0:2](-[CH3;+0:3])=[CH;+0:4]-[CH2;+0:5]-[O;H0;+0:6]-[:7]>>[:1]-[C;H0;+0:2](=[CH2;+0:3])-[CH;+0:4]=[CH2;+0:5].[:7]-[OH;+0:6]
Reaction
Core-to-Core	No scaffolds atoms were exchanged as a result of the reaction

Title	Authors	Date	PubMed ID
Structure of isoprene synthase illuminates the chemical mechanism of teragram atmospheric carbon emission.	Köksal M, Zimmer I, Schnitzler JP, Christianson DW	2010 Sep 17	20624401
Biochemical properties of isoprene synthase in poplar (Populus x canescens).	Schnitzler JP, Zimmer I, Bachl A, Arend M, Fromm J, Fischbach RJ	2005 Nov	16052321
Gene expression and characterization of isoprene synthase from Populus alba.	Sasaki K, Ohara K, Yazaki K	2005 Apr 25	15848197
Isoprene synthase activity parallels fluctuations of isoprene release during growth of Bacillus subtilis.	Sivy TL, Shirk MC, Fall R	2002 May 31	12054742
First isolation of an isoprene synthase gene from poplar and successful expression of the gene in Escherichia coli.	Miller B, Oschinski C, Zimmer W	2001 Jul	11506373