Enzyme

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EC Tree
     4. Lyases
        4.2 Carbon-oxygen lyases
            4.2.3 Acting on phosphates
ID:4.2.3.52
Description:(4S)-beta-phellandrene synthase (geranyl-diphosphate-cyclizing).
Alternative Name: (-)-beta-phellandrene synthase.
(-)-(4S)-beta-phellandrene synthase.

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 4.2.3.52
BRENDA Enzyme Link: BRENDA 4.2.3.52
KEGG Enzyme Link: KEGG4.2.3.52
BioCyc Enzyme Link: BioCyc 4.2.3.52
ExPASy Enzyme Link: ExPASy4.2.3.52
EC2PDB Enzyme Link: EC2PDB 4.2.3.52
ExplorEnz Enzyme Link: ExplorEnz 4.2.3.52
PRIAM enzyme-specific profiles Link: PRIAM 4.2.3.52
IntEnz Enzyme Link: IntEnz 4.2.3.52
MEDLINE Enzyme Link: MEDLINE 4.2.3.52
MSA:

4.2.3.52;

Phylogenetic Tree:

4.2.3.52;

Uniprot:
M-CSA:
RHEA:25492 (2E)-geranyl diphosphate = (-)-beta-phellandrene + diphosphate
RULE(radius=1) [*:1]-[C;H0;+0:2](-[*:3])=[CH;+0:4]-[*:5]-[*:6]-[C;H0;+0:7](-[CH3;+0:8])=[CH;+0:9]-[CH2;+0:10]-[O;H0;+0:11]-[*:12]>>[*:1]-[CH;+0:2](-[*:3])-[CH;+0:4]1-[*:5]-[*:6]-[C;H0;+0:7](=[CH2;+0:8])-[CH;+0:9]=[CH;+0:10]-1.[*:12]-[OH;+0:11]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
cDNA cloning, characterization, and functional expression of four new monoterpene synthase members of the Tpsd gene family from grand fir (Abies grandis).Bohlmann J, Phillips M, Ramachandiran V, Katoh S, Croteau R1999 Aug 1510441373
Hydride shifts in the biosynthesis of the p-menthane monoterpenes alpha-terpinene, gamma-terpinene, and beta-phellandrene.LaFever RE, Croteau R1993 Mar8460944
Monoterpene synthases of Pinus contorta and related conifers. A new class of terpenoid cyclase.Savage TJ, Hatch MW, Croteau R1994 Feb 118307957