EC number:4.2.3.74
| ID: | 4.2.3.74 |
|---|---|
| Description: | Presilphiperfolanol synthase. |
3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 4.2.3.74 |
| BRENDA Enzyme Link: | BRENDA 4.2.3.74 |
| KEGG Enzyme Link: | KEGG4.2.3.74 |
| BioCyc Enzyme Link: | BioCyc 4.2.3.74 |
| ExPASy Enzyme Link: | ExPASy4.2.3.74 |
| EC2PDB Enzyme Link: | EC2PDB 4.2.3.74 |
| ExplorEnz Enzyme Link: | ExplorEnz 4.2.3.74 |
| PRIAM enzyme-specific profiles Link: | PRIAM 4.2.3.74 |
| IntEnz Enzyme Link: | IntEnz 4.2.3.74 |
| MEDLINE Enzyme Link: | MEDLINE 4.2.3.74 |
| RHEA:27954 | (2E,6E)-farnesyl diphosphate + H2O = diphosphate + presilphiperfolan-8beta-ol |
| RULE(radius=1) | [*:1]-[C;H0;+0:2](-[*:3]-[*:4]-[CH;+0:5]=[C;H0;+0:6](-[*:7])-[*:8])=[CH;+0:9]-[*:10]-[*:11]-[C;H0;+0:12](-[CH3;+0:13])=[CH;+0:14]-[CH2;+0:15]-[O;H0;+0:16]-[*:17].[OH2;+0:18]>>[*:1]-[CH;+0:2]1-[*:3]-[*:4]-[CH;+0:5]2-[C;H0;+0:14]3(-[OH;+0:18])-[CH;+0:9]-1-[*:10]-[*:11]-[C;H0;+0:12]-3(-[CH3;+0:15])-[CH2;+0:13]-[C;H0;+0:6]-2(-[*:7])-[*:8].[*:17]-[OH;+0:16] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Biosynthesis of the sesquiterpene botrydial in Botrytis cinerea. Mechanism and stereochemistry of the enzymatic formation of presilphiperfolan-8beta-ol. | Wang CM, Hopson R, Lin X, Cane DE | 2009 Jun 24 | 19476353 |
| Sesquiterpene synthase from the botrydial biosynthetic gene cluster of the phytopathogen Botrytis cinerea. | Pinedo C, Wang CM, Pradier JM, Dalmais B, Choquer M, Le Pêcheur P, Morgant G, Collado IG, Cane DE, Viaud M | 2008 Dec 19 | 19035644 |