EC number:4.2.3.n2
| ID: | 4.2.3.n2 |
|---|---|
| Description: | Delta-selinene synthase. |
3D structure
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| RHEA:19525 | (2E,6E)-farnesyl diphosphate = (1S,8aR)-delta-cadinene + diphosphate |
| RULE(radius=1) | ([*:1]-[CH2;+0:2]-[O;H0;+0:3]-[*:4].[*:5]-[CH;+0:6]=[*:7].[*:8]-[CH;+0:9]=[C;H0;+0:10](-[*:11])-[*:12])>>[*:1]-[CH;+0:2](-[C;H0;+0:6](-[*:5])=[*:7])-[CH;+0:9](-[*:8])-[CH;+0:10](-[*:11])-[*:12].[*:4]-[OH;+0:3] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Sesquiterpene synthases from grand fir (Abies grandis). Comparison of constitutive and wound-induced activities, and cDNA isolation, characterization, and bacterial expression of delta-selinene synthase and gamma-humulene synthase. | Steele CL, Crock J, Bohlmann J, Croteau R | 1998 Jan 23 | 9442047 |
| Purification of (+)-delta-cadinene synthase, a sesquiterpene cyclase from bacteria-inoculated cotton foliar tissue. | Davis EM, Tsuji J, Davis GD, Pierce ML, Essenberg M | 1996 Mar | 8728715 |
| Cloning, expression, and characterization of (+)-delta-cadinene synthase: a catalyst for cotton phytoalexin biosynthesis. | Chen XY, Chen Y, Heinstein P, Davisson VJ | 1995 Dec 20 | 8554317 |
| Crystal structure of (+)-delta-cadinene synthase from Gossypium arboreum and evolutionary divergence of metal binding motifs for catalysis. | Gennadios HA, Gonzalez V, Di Costanzo L, Li A, Yu F, Miller DJ, Allemann RK, Christianson DW | 2009 Jul 7 | 19489610 |
| The molecular and biochemical basis for varietal variation in sesquiterpene content in melon (Cucumis melo L.) rinds. | Portnoy V, Benyamini Y, Bar E, Harel-Beja R, Gepstein S, Giovannoni JJ, Schaffer AA, Burger J, Tadmor Y, Lewinsohn E, Katzir N | 2008 Apr | 18264780 |
| RHEA:25440 | (2E,6E)-farnesyl diphosphate = delta-selinene + diphosphate |
| RULE(radius=1) | ([*:1]-[CH;+0:2]=[C;H0;+0:3](-[*:4])-[*:5]-[*:6]-[CH;+0:7]=[C;H0;+0:8](-[*:9])-[*:10].[*:11]=[CH;+0:12]-[CH2;+0:13]-[O;H0;+0:14]-[*:15])>>[*:15]-[OH;+0:14].[*:11]=[C;H0;+0:12]1-[CH;+0:13]=[C;H0;+0:7](-[CH;+0:8](-[*:9])-[*:10])-[*:6]-[*:5]-[C;H0;+0:3]-1(-[*:4])-[CH2;+0:2]-[*:1] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Sesquiterpene synthases from grand fir (Abies grandis). Comparison of constitutive and wound-induced activities, and cDNA isolation, characterization, and bacterial expression of delta-selinene synthase and gamma-humulene synthase. | Steele CL, Crock J, Bohlmann J, Croteau R | 1998 Jan 23 | 9442047 |
| RHEA:25444 | (2E,6E)-farnesyl diphosphate = (1E,4E)-germacrene B + diphosphate |
| RULE(radius=1) | ([*:1]-[CH2;+0:2]-[O;H0;+0:3]-[*:4].[*:5]-[CH;+0:6]=[*:7])>>[*:1]-[CH2;+0:2]-[C;H0;+0:6](-[*:5])=[*:7].[*:4]-[OH;+0:3] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Sesquiterpene synthases from grand fir (Abies grandis). Comparison of constitutive and wound-induced activities, and cDNA isolation, characterization, and bacterial expression of delta-selinene synthase and gamma-humulene synthase. | Steele CL, Crock J, Bohlmann J, Croteau R | 1998 Jan 23 | 9442047 |
| Genetic control and evolution of sesquiterpene biosynthesis in Lycopersicon esculentum and L. hirsutum. | van Der Hoeven RS, Monforte AJ, Breeden D, Tanksley SD, Steffens JC | 2000 Nov | 11090225 |
| RHEA:25448 | (2E,6E)-farnesyl diphosphate = (+)-guaia-6,9-diene + diphosphate |
| RULE(radius=1) | [*:1]-[C;H0;+0:2](-[CH2;+0:3]-[CH2;+0:4]-[CH;+0:5]=[C;H0;+0:6](-[*:7])-[*:8])=[CH;+0:9]-[*:10]-[CH2;+0:11]-[*:12]=[*:13]-[CH2;+0:14]-[O;H0;+0:15]-[*:16]>>[*:1]-[CH;+0:2]1-[CH2;+0:9]-[*:10]-[CH;+0:11]2-[*:12]=[*:13]-[CH2;+0:14]-[C;H0;+0:5](-[CH;+0:6](-[*:7])-[*:8])=[CH;+0:4]-[CH;+0:3]-2-1.[*:16]-[OH;+0:15] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Sesquiterpene synthases from grand fir (Abies grandis). Comparison of constitutive and wound-induced activities, and cDNA isolation, characterization, and bacterial expression of delta-selinene synthase and gamma-humulene synthase. | Steele CL, Crock J, Bohlmann J, Croteau R | 1998 Jan 23 | 9442047 |
| RHEA:25452 | (2E,6E)-farnesyl diphosphate = diphosphate + germacrene A |
| RULE(radius=1) | ([*:1]-[CH2;+0:2]-[O;H0;+0:3]-[*:4].[*:5]-[CH;+0:6]=[C;H0;+0:7](-[*:8])-[CH3;+0:9])>>[*:1]-[CH2;+0:2]-[CH;+0:6](-[*:5])-[C;H0;+0:7](-[*:8])=[CH2;+0:9].[*:4]-[OH;+0:3] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| Sesquiterpene synthases from grand fir (Abies grandis). Comparison of constitutive and wound-induced activities, and cDNA isolation, characterization, and bacterial expression of delta-selinene synthase and gamma-humulene synthase. | Steele CL, Crock J, Bohlmann J, Croteau R | 1998 Jan 23 | 9442047 |