Enzyme

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     5. Isomerases
        5.3 Intramolecular oxidoreductases
            5.3.99 Other intramolecular oxidoreductases
ID:5.3.99.8
Description:Capsanthin/capsorubin synthase.
Alternative Name: Ketoxanthophyll synthase.
CCS.
Capsanthin-capsorubin synthase.

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 5.3.99.8
BRENDA Enzyme Link: BRENDA 5.3.99.8
KEGG Enzyme Link: KEGG5.3.99.8
BioCyc Enzyme Link: BioCyc 5.3.99.8
ExPASy Enzyme Link: ExPASy5.3.99.8
EC2PDB Enzyme Link: EC2PDB 5.3.99.8
ExplorEnz Enzyme Link: ExplorEnz 5.3.99.8
PRIAM enzyme-specific profiles Link: PRIAM 5.3.99.8
IntEnz Enzyme Link: IntEnz 5.3.99.8
MEDLINE Enzyme Link: MEDLINE 5.3.99.8
MSA:

5.3.99.8;

Phylogenetic Tree:

5.3.99.8;

Uniprot:
M-CSA:
RHEA:21752 all-trans-violaxanthin = all-trans-capsorubin
RULE(radius=1) ([*:1]-[C;H0;+0:2]1(-[*:3])-[O;H0;+0:4]-[C;H0;+0:5]-1(-[*:6])-[C;H0;+0:7](-[*:8])(-[*:9])-[*:10].[*:11]-[C;H0;+0:12]1(-[C;H0;+0:13](-[*:14])(-[*:15])-[*:16])-[O;H0;+0:17]-[C;H0;+0:18]-1(-[*:19])-[*:20])>>([*:1]-[C;H0;+0:2](-[*:3])(-[C;H0;+0:5](-[*:6])=[O;H0;+0:4])-[C;H0;+0:7](-[*:8])(-[*:9])-[*:10].[*:11]-[C;H0;+0:12](=[O;H0;+0:17])-[C;H0;+0:18](-[*:19])(-[*:20])-[C;H0;+0:13](-[*:14])(-[*:15])-[*:16])
Reaction
Core-to-Core More

References

TitleAuthorsDatePubMed ID
The capsanthin-capsorubin synthase gene: a candidate gene for the y locus controlling the red fruit colour in pepper.Lefebvre V, Kuntz M, Camara B, Palloix A1998 Mar9526511
Xanthophyll biosynthesis in chromoplasts: isolation and molecular cloning of an enzyme catalyzing the conversion of 5,6-epoxycarotenoid into ketocarotenoid.Bouvier F, Hugueney P, d'Harlingue A, Kuntz M, Camara B1994 Jul7920703
Characterization of plant carotenoid cyclases as members of the flavoprotein family functioning with no net redox change.Mialoundama AS, Heintz D, Jadid N, Nkeng P, Rahier A, Deli J, Camara B, Bouvier F2010 Jul20460582
[Molecular cloning of full length capsanthin/capsorubin synthase homologous gene from orange (Citrus sinensis)].Xu CJ, Chen DM, Zhang SL2001 Jun12549109

RHEA:17373 all-trans-antheraxanthin = all-trans-capsanthin
RULE(radius=1) [*:1]-[C;H0;+0:2]1(-[C;H0;+0:3](-[*:4])(-[*:5])-[*:6])-[O;H0;+0:7]-[C;H0;+0:8]-1(-[*:9])-[*:10]>>[*:1]-[C;H0;+0:2](=[O;H0;+0:7])-[C;H0;+0:8](-[*:9])(-[*:10])-[C;H0;+0:3](-[*:4])(-[*:5])-[*:6]
Reaction
Core-to-Core More

References

TitleAuthorsDatePubMed ID
The capsanthin-capsorubin synthase gene: a candidate gene for the y locus controlling the red fruit colour in pepper.Lefebvre V, Kuntz M, Camara B, Palloix A1998 Mar9526511
Molecular analysis of carotenoid cyclase inhibition.Bouvier F, d'Harlingue A, Camara B1997 Oct 19328284
Xanthophyll biosynthesis in chromoplasts: isolation and molecular cloning of an enzyme catalyzing the conversion of 5,6-epoxycarotenoid into ketocarotenoid.Bouvier F, Hugueney P, d'Harlingue A, Kuntz M, Camara B1994 Jul7920703
Characterization of plant carotenoid cyclases as members of the flavoprotein family functioning with no net redox change.Mialoundama AS, Heintz D, Jadid N, Nkeng P, Rahier A, Deli J, Camara B, Bouvier F2010 Jul20460582
[Molecular cloning of full length capsanthin/capsorubin synthase homologous gene from orange (Citrus sinensis)].Xu CJ, Chen DM, Zhang SL2001 Jun12549109