EC number:5.4.4.6
Enzyme
Download| EC Tree |
| 5. Isomerases |
| 5.4 Intramolecular transferases |
| 5.4.4 Transferring hydroxy groups |
| ID: | 5.4.4.6 |
|---|---|
| Description: | 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase. |
| Alternative Name: |
5,8-dihydroxy-9,12-octadecadienoate-forming). (8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate mutase ((7S,8S,9Z,12Z)- |
3D structure
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External Links
| UniProtKB Enzyme Link: | UniProtKB 5.4.4.6 |
| BRENDA Enzyme Link: | BRENDA 5.4.4.6 |
| KEGG Enzyme Link: | KEGG5.4.4.6 |
| BioCyc Enzyme Link: | BioCyc 5.4.4.6 |
| ExPASy Enzyme Link: | ExPASy5.4.4.6 |
| EC2PDB Enzyme Link: | EC2PDB 5.4.4.6 |
| ExplorEnz Enzyme Link: | ExplorEnz 5.4.4.6 |
| PRIAM enzyme-specific profiles Link: | PRIAM 5.4.4.6 |
| IntEnz Enzyme Link: | IntEnz 5.4.4.6 |
| MEDLINE Enzyme Link: | MEDLINE 5.4.4.6 |
| RHEA:25399 | (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate = (7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate |
| RULE(radius=1) | [*:1]-[CH2;+0:2]-[*:3]-[O;H0;+0:4]-[OH;+0:5]>>[*:1]-[CH;+0:2](-[OH;+0:5])-[*:3]-[OH;+0:4] |
| Reaction |  |
| Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
References
| Title | Authors | Date | PubMed ID |
|---|---|---|---|
| A protein radical and ferryl intermediates are generated by linoleate diol synthase, a ferric hemeprotein with dioxygenase and hydroperoxide isomerase activities. | Su C, Sahlin M, Oliw EH | 1998 Aug 14 | 9694817 |
| Sequential oxygenation of linoleic acid in the fungus Gaeumannomyces graminis: stereochemistry of dioxygenase and hydroperoxide isomerase reactions. | Hamberg M, Zhang LY, Brodowsky ID, Oliw EH | 1994 Feb 15 | 8117115 |