Enzyme

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     5. Isomerases
        5.5 Intramolecular lyases
            5.5.1 Intramolecular lyases (only sub-subclass identified to date)
ID:5.5.1.29
Description:(+)-kolavenyl diphosphate synthase.

3D structure

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References

External Links

UniProtKB Enzyme Link: UniProtKB 5.5.1.29
BRENDA Enzyme Link: BRENDA 5.5.1.29
KEGG Enzyme Link: KEGG5.5.1.29
BioCyc Enzyme Link: BioCyc 5.5.1.29
ExPASy Enzyme Link: ExPASy5.5.1.29
EC2PDB Enzyme Link: EC2PDB 5.5.1.29
ExplorEnz Enzyme Link: ExplorEnz 5.5.1.29
PRIAM enzyme-specific profiles Link: PRIAM 5.5.1.29
IntEnz Enzyme Link: IntEnz 5.5.1.29
MEDLINE Enzyme Link: MEDLINE 5.5.1.29
MSA:

5.5.1.29;

Phylogenetic Tree:

5.5.1.29;

Uniprot:
M-CSA:
RHEA:54676 all-trans-geranylgeranyl diphosphate = (+)-kolavenyl diphosphate
RULE(radius=1) ([*:1]-[CH;+0:2]=[C;H0;+0:3](-[*:4])-[*:5]-[*:6]-[CH;+0:7]=[C;H0;+0:8](-[*:9])-[CH3;+0:10].[*:11]=[C;H0;+0:12](-[*:13])-[CH3;+0:14])>>[*:1]-[C;H0;+0:2]1(-[CH3;+0:10])-[CH;+0:3](-[*:4])-[*:5]-[*:6]-[C;H0;+0:7](-[CH3;+0:14])(-[C;H0;+0:12](=[*:11])-[*:13])-[CH;+0:8]-1-[*:9]
Reaction
Core-to-Core No scaffolds atoms were exchanged as a result of the reaction

References

TitleAuthorsDatePubMed ID
Identification of a new diterpene biosynthetic gene cluster that produces O-methylkolavelool in Herpetosiphon aurantiacus.Nakano C, Oshima M, Kurashima N, Hoshino T2015 Mar 2325694050