EC Tree |
5. Isomerases |
5.5 Intramolecular lyases |
5.5.1 Intramolecular lyases (only sub-subclass identified to date) |
ID: | 5.5.1.8 |
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Description: | (+)-bornyl diphosphate synthase. |
Alternative Name: |
Geranyl-diphosphate cyclase. Bornyl pyrophosphate synthetase. Bornyl pyrophosphate synthase. |
Cath: | 1.10.600.10; 1.50.10.130; |
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Note: Use your mouse to drag, rotate, and zoom in and out of the structure. Mouse-over to identify atoms and bonds. Mouse controls documentation.UniProtKB Enzyme Link: | UniProtKB 5.5.1.8 |
BRENDA Enzyme Link: | BRENDA 5.5.1.8 |
KEGG Enzyme Link: | KEGG5.5.1.8 |
BioCyc Enzyme Link: | BioCyc 5.5.1.8 |
ExPASy Enzyme Link: | ExPASy5.5.1.8 |
EC2PDB Enzyme Link: | EC2PDB 5.5.1.8 |
ExplorEnz Enzyme Link: | ExplorEnz 5.5.1.8 |
PRIAM enzyme-specific profiles Link: | PRIAM 5.5.1.8 |
IntEnz Enzyme Link: | IntEnz 5.5.1.8 |
MEDLINE Enzyme Link: | MEDLINE 5.5.1.8 |
RHEA:18209 | (2E)-geranyl diphosphate = (2S)-bornyl diphosphate |
RULE(radius=1) | [*:1]-[C;H0;+0:2](-[*:3])=[CH;+0:4]-[*:5]-[*:6]-[C;H0;+0:7](-[CH3;+0:8])=[CH;+0:9]-[CH2;+0:10]-[*:11]>>[*:1]-[C;H0;+0:2]1(-[*:3])-[CH;+0:7]2-[*:6]-[*:5]-[C;H0;+0:4]-1(-[CH3;+0:8])-[CH;+0:10](-[*:11])-[CH2;+0:9]-2 |
Reaction | ![]() |
Core-to-Core | No scaffolds atoms were exchanged as a result of the reaction |
Title | Authors | Date | PubMed ID |
---|---|---|---|
Monoterpene synthases from common sage (Salvia officinalis). cDNA isolation, characterization, and functional expression of (+)-sabinene synthase, 1,8-cineole synthase, and (+)-bornyl diphosphate synthase. | Wise ML, Savage TJ, Katahira E, Croteau R | 1998 Jun 12 | 9614092 |
Biotransformation of limonene by bacteria, fungi, yeasts, and plants. | Duetz WA, Bouwmeester H, van Beilen JB, Witholt B | 2003 May | 12743755 |
Bornyl diphosphate synthase: structure and strategy for carbocation manipulation by a terpenoid cyclase. | Whittington DA, Wise ML, Urbansky M, Coates RM, Croteau RB, Christianson DW | 2002 Nov 26 | 12432096 |